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dc.contributor.authorValera, Silvia
dc.contributor.authorBode, Bela Ernest
dc.date.accessioned2014-12-03T14:31:06Z
dc.date.available2014-12-03T14:31:06Z
dc.date.issued2014-12-03
dc.identifier.citationValera , S & Bode , B E 2014 , ' Strategies for synthesis of yardsticks and abaci for nanometre distance measurements by pulsed EPR ' , Molecules , vol. 19 , no. 12 , pp. 20227-20256 . https://doi.org/10.3390/molecules191220227en
dc.identifier.issn1420-3049
dc.identifier.otherPURE: 158446954
dc.identifier.otherPURE UUID: 77e5e03e-9a42-486c-99c0-723b904933dc
dc.identifier.otherWOS: 000346793200054
dc.identifier.otherScopus: 84919774846
dc.identifier.urihttp://hdl.handle.net/10023/5863
dc.descriptionSilvia Valera is grateful for support by EPSRC and Bela E. Bode acknowledges support by EastCHEM.en
dc.description.abstractPulsed electron paramagnetic resonance (EPR) techniques have been found to be an efficient tool for elucidation of structure in complex biological systems as they give access to distances in the nanometre range. These measurements can provide additional structural information such as relative orientations, structural flexibility or aggregation states. A wide variety of model systems for calibration and optimisation of pulsed experiments has been synthesised. Their design is based on mimicking biological systems or materials in specific properties such as the distances themselves and the distance distributions. Here, we review selected approaches to the synthesis of chemical systems bearing two or more spin centres, such as nitroxide or trityl radicals, metal ions or combinations thereof and sketch their application in pulsed EPR distance measurements.
dc.format.extent30
dc.language.isoeng
dc.relation.ispartofMoleculesen
dc.rights© 2014 by the authors; licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution license (http://creativecommons.org/licenses/by/4.0/).en
dc.subjectModel systemsen
dc.subjectSynthesisen
dc.subjectEPR distance measurementsen
dc.subjectNitroxide and trityl radicalsen
dc.subjectMetal centresen
dc.subjectQD Chemistryen
dc.subject.lccQDen
dc.titleStrategies for synthesis of yardsticks and abaci for nanometre distance measurements by pulsed EPRen
dc.typeJournal itemen
dc.description.versionPublisher PDFen
dc.contributor.institutionUniversity of St Andrews.School of Chemistryen
dc.contributor.institutionUniversity of St Andrews.Centre of Magnetic Resonanceen
dc.contributor.institutionUniversity of St Andrews.Biomedical Sciences Research Complexen
dc.contributor.institutionUniversity of St Andrews.EaSTCHEMen
dc.identifier.doihttps://doi.org/10.3390/molecules191220227
dc.description.statusPeer revieweden


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