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Strategies for synthesis of yardsticks and abaci for nanometre distance measurements by pulsed EPR
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dc.contributor.author | Valera, Silvia | |
dc.contributor.author | Bode, Bela Ernest | |
dc.date.accessioned | 2014-12-03T14:31:06Z | |
dc.date.available | 2014-12-03T14:31:06Z | |
dc.date.issued | 2014-12-03 | |
dc.identifier.citation | Valera , S & Bode , B E 2014 , ' Strategies for synthesis of yardsticks and abaci for nanometre distance measurements by pulsed EPR ' , Molecules , vol. 19 , no. 12 , pp. 20227-20256 . https://doi.org/10.3390/molecules191220227 | en |
dc.identifier.issn | 1420-3049 | |
dc.identifier.other | PURE: 158446954 | |
dc.identifier.other | PURE UUID: 77e5e03e-9a42-486c-99c0-723b904933dc | |
dc.identifier.other | WOS: 000346793200054 | |
dc.identifier.other | Scopus: 84919774846 | |
dc.identifier.uri | https://hdl.handle.net/10023/5863 | |
dc.description | Silvia Valera is grateful for support by EPSRC and Bela E. Bode acknowledges support by EastCHEM. | en |
dc.description.abstract | Pulsed electron paramagnetic resonance (EPR) techniques have been found to be an efficient tool for elucidation of structure in complex biological systems as they give access to distances in the nanometre range. These measurements can provide additional structural information such as relative orientations, structural flexibility or aggregation states. A wide variety of model systems for calibration and optimisation of pulsed experiments has been synthesised. Their design is based on mimicking biological systems or materials in specific properties such as the distances themselves and the distance distributions. Here, we review selected approaches to the synthesis of chemical systems bearing two or more spin centres, such as nitroxide or trityl radicals, metal ions or combinations thereof and sketch their application in pulsed EPR distance measurements. | |
dc.format.extent | 30 | |
dc.language.iso | eng | |
dc.relation.ispartof | Molecules | en |
dc.rights | © 2014 by the authors; licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution license (http://creativecommons.org/licenses/by/4.0/). | en |
dc.subject | Model systems | en |
dc.subject | Synthesis | en |
dc.subject | EPR distance measurements | en |
dc.subject | Nitroxide and trityl radicals | en |
dc.subject | Metal centres | en |
dc.subject | QD Chemistry | en |
dc.subject.lcc | QD | en |
dc.title | Strategies for synthesis of yardsticks and abaci for nanometre distance measurements by pulsed EPR | en |
dc.type | Journal item | en |
dc.description.version | Publisher PDF | en |
dc.contributor.institution | University of St Andrews. School of Chemistry | en |
dc.contributor.institution | University of St Andrews. Centre of Magnetic Resonance | en |
dc.contributor.institution | University of St Andrews. Biomedical Sciences Research Complex | en |
dc.contributor.institution | University of St Andrews. EaSTCHEM | en |
dc.identifier.doi | https://doi.org/10.3390/molecules191220227 | |
dc.description.status | Peer reviewed | en |
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