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Poly[[chlorido-(1,10-phenanthroline-κ2N,N′)copper(II)]-μ3-1,1,3,3-tetra-cyano-2-eth-oxy-propenido- κ3N:N′:N′′] : coordination polymer sheets linked into bilayers by hydrogen bonds
Item metadata
dc.contributor.author | Setifi, Z. | |
dc.contributor.author | Setifi, F. | |
dc.contributor.author | El Ammari, L. | |
dc.contributor.author | El-Ghozzi, M. | |
dc.contributor.author | Sopková-De Oliveira Santos, J. | |
dc.contributor.author | Merazig, H. | |
dc.contributor.author | Glidewell, C. | |
dc.date.accessioned | 2014-08-27T11:01:00Z | |
dc.date.available | 2014-08-27T11:01:00Z | |
dc.date.issued | 2014-01-01 | |
dc.identifier.citation | Setifi , Z , Setifi , F , El Ammari , L , El-Ghozzi , M , Sopková-De Oliveira Santos , J , Merazig , H & Glidewell , C 2014 , ' Poly[[chlorido-(1,10-phenanthroline-κ 2 N,N′)copper(II)]-μ 3 -1,1,3,3-tetra-cyano-2-eth-oxy-propenido- κ 3 N:N′:N′′] : coordination polymer sheets linked into bilayers by hydrogen bonds ' , Acta Crystallographica Section C: Crystal Structure Communications , vol. 70 , no. 1 , pp. 19-22 . https://doi.org/10.1107/S2053229613032804 | en |
dc.identifier.issn | 0108-2701 | |
dc.identifier.other | PURE: 143715473 | |
dc.identifier.other | PURE UUID: 2228b5bc-83b3-40fb-bcef-78892ede1361 | |
dc.identifier.other | Scopus: 84901925164 | |
dc.identifier.other | WOS: 000331291400006 | |
dc.identifier.uri | https://hdl.handle.net/10023/5252 | |
dc.description | The authors acknowledge the Algerian DG–RSDT (Direction Generale de la Recherche Scientifique et du Developpement Technologique) and the Algerian ATRST (Agence Thematique de Recherche en Sciences et Technologie; PNR project) for financial support. ZS thanks Sandra Lebaroud for her help in preparing the manuscript and the Unit of Support for Technical and Scientific Research (UATRS, CNRST) for the X-ray measurements. | en |
dc.description.abstract | In the title compound, [Cu(C9H5N4O)Cl(C12H8N2)] n or [Cu(tcnoet)Cl(phen)] n , where phen is 1,10-phenanthroline and tcnoet is 1,1,3,3-tetra-cyano-2-eth- oxy-propenide, the axially elongated (4 + 2) coordination polyhedron around the CuII centre contains N atoms from three different tcnoet ligands. The resulting coordination polymer takes the form of sheets which are linked in pairs by a single C - H⋯N hydrogen bond to form bilayers. The bond lengths provide evidence for significant bond fixation in the phen ligand and extensive electronic delocalization in the tcnoet ligand, where the two -C(CN)2 units are rotated, in conrotatory fashion, out of the plane of the central C3O fragment. | |
dc.format.extent | 4 | |
dc.language.iso | eng | |
dc.relation.ispartof | Acta Crystallographica Section C: Crystal Structure Communications | en |
dc.rights | © 2014 International Union of Crystallography. | en |
dc.subject | Crystal structure | en |
dc.subject | Coordination polymer | en |
dc.subject | Hydrogen bonding | en |
dc.subject | Anionic polynitrile ligands | en |
dc.subject | Tcnoet ligands | en |
dc.subject | 1,1,3,3-tetracyano-2-ethoxypropenide | en |
dc.subject | (4+2) coordination polyhedron | en |
dc.subject | Copper complex | en |
dc.subject | QD Chemistry | en |
dc.subject.lcc | QD | en |
dc.title | Poly[[chlorido-(1,10-phenanthroline-κ2N,N′)copper(II)]-μ3-1,1,3,3-tetra-cyano-2-eth-oxy-propenido- κ3N:N′:N′′] : coordination polymer sheets linked into bilayers by hydrogen bonds | en |
dc.type | Journal article | en |
dc.description.version | Publisher PDF | en |
dc.contributor.institution | University of St Andrews. School of Chemistry | en |
dc.identifier.doi | https://doi.org/10.1107/S2053229613032804 | |
dc.description.status | Peer reviewed | en |
dc.identifier.url | http://www.scopus.com/inward/record.url?eid=2-s2.0-84901925164&partnerID=8YFLogxK | en |
dc.identifier.url | http://scripts.iucr.org/cgi-bin/sendsup?sk3522 | en |
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