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Poly[[chlorido-(1,10-phenanthroline-κ2N,N′)copper(II)]-μ3-1,1,3,3-tetra-cyano-2-eth-oxy-propenido- κ3N:N′:N′′] : coordination polymer sheets linked into bilayers by hydrogen bonds

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Glidewell_2014_SC_Poly.pdf (541.4Kb)
Date
01/01/2014
Author
Setifi, Z.
Setifi, F.
El Ammari, L.
El-Ghozzi, M.
Sopková-De Oliveira Santos, J.
Merazig, H.
Glidewell, C.
Keywords
Crystal structure
Coordination polymer
Hydrogen bonding
Anionic polynitrile ligands
Tcnoet ligands
1,1,3,3-tetracyano-2-ethoxypropenide
(4+2) coordination polyhedron
Copper complex
QD Chemistry
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Abstract
In the title compound, [Cu(C9H5N4O)Cl(C12H8N2)] n or [Cu(tcnoet)Cl(phen)] n , where phen is 1,10-phenanthroline and tcnoet is 1,1,3,3-tetra-cyano-2-eth- oxy-propenide, the axially elongated (4 + 2) coordination polyhedron around the CuII centre contains N atoms from three different tcnoet ligands. The resulting coordination polymer takes the form of sheets which are linked in pairs by a single C - H⋯N hydrogen bond to form bilayers. The bond lengths provide evidence for significant bond fixation in the phen ligand and extensive electronic delocalization in the tcnoet ligand, where the two -C(CN)2 units are rotated, in conrotatory fashion, out of the plane of the central C3O fragment.
Citation
Setifi , Z , Setifi , F , El Ammari , L , El-Ghozzi , M , Sopková-De Oliveira Santos , J , Merazig , H & Glidewell , C 2014 , ' Poly[[chlorido-(1,10-phenanthroline-κ 2 N,N′)copper(II)]-μ 3 -1,1,3,3-tetra-cyano-2-eth-oxy-propenido- κ 3 N:N′:N′′] : coordination polymer sheets linked into bilayers by hydrogen bonds ' , Acta Crystallographica Section C: Crystal Structure Communications , vol. 70 , no. 1 , pp. 19-22 . https://doi.org/10.1107/S2053229613032804
Publication
Acta Crystallographica Section C: Crystal Structure Communications
Status
Peer reviewed
DOI
https://doi.org/10.1107/S2053229613032804
ISSN
0108-2701
Type
Journal article
Rights
© 2014 International Union of Crystallography.
Description
The authors acknowledge the Algerian DG–RSDT (Direction Generale de la Recherche Scientifique et du Developpement Technologique) and the Algerian ATRST (Agence Thematique de Recherche en Sciences et Technologie; PNR project) for financial support. ZS thanks Sandra Lebaroud for her help in preparing the manuscript and the Unit of Support for Technical and Scientific Research (UATRS, CNRST) for the X-ray measurements.
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  • University of St Andrews Research
URL
http://www.scopus.com/inward/record.url?eid=2-s2.0-84901925164&partnerID=8YFLogxK
http://scripts.iucr.org/cgi-bin/sendsup?sk3522
URI
http://hdl.handle.net/10023/5252

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