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New structural units in molybdenum oxyfluoride chemistry

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dc.contributor.authorAldous, David W.
dc.contributor.authorLightfoot, Philip
dc.date.accessioned2013-06-18T09:01:02Z
dc.date.available2013-06-18T09:01:02Z
dc.date.issued2012-12
dc.identifier42715965
dc.identifierd375f22c-62d5-4792-b277-3d8d84f35805
dc.identifier000312234500018
dc.identifier84868590179
dc.identifier.citationAldous , D W & Lightfoot , P 2012 , ' New structural units in molybdenum oxyfluoride chemistry ' , Journal of Fluorine Chemistry , vol. 144 , pp. 108-113 . https://doi.org/10.1016/j.jfluchem.2012.07.018en
dc.identifier.issn0022-1139
dc.identifier.otherORCID: /0000-0001-7048-3982/work/59464469
dc.identifier.urihttps://hdl.handle.net/10023/3712
dc.descriptionThis article was supported with EPSRC funding.en
dc.description.abstractThe solvothermal syntheses and crystal structures of five new molybdenum oxyfluorides are presented. These exhibit three novel structural units, each containing Mo in a reduced oxidation state: a dimeric [MO2O4F2(C2H8N2)(2)] unit (Mo4+), a tetrameric [Mo4O8F10](6-) unit (Mo5+) and an infinite chain [MoOF3](-) unit (Mo4+). Mo-Mo bonding is observed in each of the new building units.
dc.format.extent6
dc.format.extent689661
dc.language.isoeng
dc.relation.ispartofJournal of Fluorine Chemistryen
dc.subjectMolybdenum oxyfluorideen
dc.subjectSolvothermal synthesisen
dc.subjectMetal–metal bondingen
dc.subjectCrystal structureen
dc.subjectQD Chemistryen
dc.subject.lccQDen
dc.titleNew structural units in molybdenum oxyfluoride chemistryen
dc.typeJournal articleen
dc.contributor.institutionUniversity of St Andrews. School of Chemistryen
dc.contributor.institutionUniversity of St Andrews. EaSTCHEMen
dc.identifier.doi10.1016/j.jfluchem.2012.07.018
dc.description.statusPeer revieweden


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