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New structural units in molybdenum oxyfluoride chemistry

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dc.contributor.authorAldous, David W.
dc.contributor.authorLightfoot, Philip
dc.date.accessioned2013-06-18T09:01:02Z
dc.date.available2013-06-18T09:01:02Z
dc.date.issued2012-12
dc.identifier.citationAldous , D W & Lightfoot , P 2012 , ' New structural units in molybdenum oxyfluoride chemistry ' , Journal of Fluorine Chemistry , vol. 144 , pp. 108-113 . https://doi.org/10.1016/j.jfluchem.2012.07.018en
dc.identifier.issn0022-1139
dc.identifier.otherPURE: 42715965
dc.identifier.otherPURE UUID: d375f22c-62d5-4792-b277-3d8d84f35805
dc.identifier.otherWOS: 000312234500018
dc.identifier.otherScopus: 84868590179
dc.identifier.otherORCID: /0000-0001-7048-3982/work/59464469
dc.identifier.urihttp://hdl.handle.net/10023/3712
dc.descriptionThis article was supported with EPSRC funding.en
dc.description.abstractThe solvothermal syntheses and crystal structures of five new molybdenum oxyfluorides are presented. These exhibit three novel structural units, each containing Mo in a reduced oxidation state: a dimeric [MO2O4F2(C2H8N2)(2)] unit (Mo4+), a tetrameric [Mo4O8F10](6-) unit (Mo5+) and an infinite chain [MoOF3](-) unit (Mo4+). Mo-Mo bonding is observed in each of the new building units.
dc.format.extent6
dc.language.isoeng
dc.relation.ispartofJournal of Fluorine Chemistryen
dc.rightsCopyright © 2012 Elsevier. This is the author’s version of a work that was accepted for publication in Journal of Fluorine Chemistry. Changes resulting from the publishing process, such as peer review, editing, corrections, structural formatting, and other quality control mechanisms may not be reflected in this document. Changes may have been made to this work since it was submitted for publication. A definitive version was subsequently published in Journal of Fluorine Chemistry, Vol 144, (2012). DOI http://dx.doi.org/10.1016/j.jfluchem.2012.07.018en
dc.subjectMolybdenum oxyfluorideen
dc.subjectSolvothermal synthesisen
dc.subjectMetal–metal bondingen
dc.subjectCrystal structureen
dc.subjectQD Chemistryen
dc.subject.lccQDen
dc.titleNew structural units in molybdenum oxyfluoride chemistryen
dc.typeJournal articleen
dc.description.versionPostprinten
dc.contributor.institutionUniversity of St Andrews. School of Chemistryen
dc.contributor.institutionUniversity of St Andrews. EaSTCHEMen
dc.identifier.doihttps://doi.org/10.1016/j.jfluchem.2012.07.018
dc.description.statusPeer revieweden


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