New structural units in molybdenum oxyfluoride chemistry

Aldous, David W.; Lightfoot, Philip

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Date

12/2012

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Abstract

The solvothermal syntheses and crystal structures of five new molybdenum oxyfluorides are presented. These exhibit three novel structural units, each containing Mo in a reduced oxidation state: a dimeric [MO2O4F2(C2H8N2)(2)] unit (Mo4+), a tetrameric [Mo4O8F10](6-) unit (Mo5+) and an infinite chain [MoOF3](-) unit (Mo4+). Mo-Mo bonding is observed in each of the new building units.

Citation

Aldous , D W & Lightfoot , P 2012 , ' New structural units in molybdenum oxyfluoride chemistry ' , Journal of Fluorine Chemistry , vol. 144 , pp. 108-113 . https://doi.org/10.1016/j.jfluchem.2012.07.018

Publication

Journal of Fluorine Chemistry

Status

Peer reviewed

DOI

https://doi.org/10.1016/j.jfluchem.2012.07.018

ISSN

0022-1139

Type

Journal article

Rights

Copyright © 2012 Elsevier. This is the author’s version of a work that was accepted for publication in Journal of Fluorine Chemistry. Changes resulting from the publishing process, such as peer review, editing, corrections, structural formatting, and other quality control mechanisms may not be reflected in this document. Changes may have been made to this work since it was submitted for publication. A definitive version was subsequently published in Journal of Fluorine Chemistry, Vol 144, (2012). DOI http://dx.doi.org/10.1016/j.jfluchem.2012.07.018

Description

This article was supported with EPSRC funding.

Collections

University of St Andrews Research

URI

http://hdl.handle.net/10023/3712