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Extending the utility of [Pd(NHC)(cinnamyl)Cl] precatalysts : Direct arylation of heterocycles

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dc.contributor.authorMartin, Anthony
dc.contributor.authorChartoire, Anthony Raymond Georges
dc.contributor.authorSlawin, Alexandra Martha Zoya
dc.contributor.authorNolan, Steven Patrick
dc.date.accessioned2012-11-20T16:31:02Z
dc.date.available2012-11-20T16:31:02Z
dc.date.issued2012-09-27
dc.identifier30087527
dc.identifier3794011c-ed1b-4b89-8c9c-9e3f721b15f1
dc.identifier000309591800001
dc.identifier84867219499
dc.identifier.citationMartin , A , Chartoire , A R G , Slawin , A M Z & Nolan , S P 2012 , ' Extending the utility of [Pd(NHC)(cinnamyl)Cl] precatalysts : Direct arylation of heterocycles ' , Beilstein Journal of Organic Chemistry , vol. 8 , pp. 1637-1643 . https://doi.org/10.3762/bjoc.8.187en
dc.identifier.issn1860-5397
dc.identifier.otherORCID: /0000-0002-9527-6418/work/56861423
dc.identifier.urihttps://hdl.handle.net/10023/3257
dc.description.abstractThe use of [Pd(NHC)(cinnamyl)Cl] precatalysts in the direct arylation of heterocycles has been investigated. Among four different precatalysts, [Pd(SIPr)(cinnamyl)Cl] proved to be the most efficient promoter of the reaction. The C–H functionalization of sulfuror nitrogen-containing heterocycles has been achieved at low catalyst loadings. These catalyst charges range from 0.1 to 0.01 mol % palladium.
dc.format.extent7
dc.format.extent427214
dc.language.isoeng
dc.relation.ispartofBeilstein Journal of Organic Chemistryen
dc.subjectC-H functionalizationen
dc.subjectDirect arylationen
dc.subjectHeterocyclesen
dc.subjectN-heterocyclicen
dc.subjectCarbenesen
dc.subjectPalladiumen
dc.subjectQD Chemistryen
dc.subject.lccQDen
dc.titleExtending the utility of [Pd(NHC)(cinnamyl)Cl] precatalysts : Direct arylation of heterocyclesen
dc.typeJournal articleen
dc.contributor.sponsorEPSRCen
dc.contributor.institutionUniversity of St Andrews. School of Chemistryen
dc.contributor.institutionUniversity of St Andrews. EaSTCHEMen
dc.identifier.doihttps://doi.org/10.3762/bjoc.8.187
dc.description.statusPeer revieweden
dc.identifier.grantnumberEP/J011053/1en


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