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Extending the utility of [Pd(NHC)(cinnamyl)Cl] precatalysts : Direct arylation of heterocycles

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dc.contributor.authorMartin, Anthony
dc.contributor.authorChartoire, Anthony Raymond Georges
dc.contributor.authorSlawin, Alexandra Martha Zoya
dc.contributor.authorNolan, Steven Patrick
dc.date.accessioned2012-11-20T16:31:02Z
dc.date.available2012-11-20T16:31:02Z
dc.date.issued2012-09-27
dc.identifier.citationMartin , A , Chartoire , A R G , Slawin , A M Z & Nolan , S P 2012 , ' Extending the utility of [Pd(NHC)(cinnamyl)Cl] precatalysts : Direct arylation of heterocycles ' , Beilstein Journal of Organic Chemistry , vol. 8 , pp. 1637-1643 . https://doi.org/10.3762/bjoc.8.187en
dc.identifier.issn1860-5397
dc.identifier.otherPURE: 30087527
dc.identifier.otherPURE UUID: 3794011c-ed1b-4b89-8c9c-9e3f721b15f1
dc.identifier.otherWOS: 000309591800001
dc.identifier.otherScopus: 84867219499
dc.identifier.otherORCID: /0000-0002-9527-6418/work/56861423
dc.identifier.urihttps://hdl.handle.net/10023/3257
dc.description.abstractThe use of [Pd(NHC)(cinnamyl)Cl] precatalysts in the direct arylation of heterocycles has been investigated. Among four different precatalysts, [Pd(SIPr)(cinnamyl)Cl] proved to be the most efficient promoter of the reaction. The C–H functionalization of sulfuror nitrogen-containing heterocycles has been achieved at low catalyst loadings. These catalyst charges range from 0.1 to 0.01 mol % palladium.
dc.format.extent7
dc.language.isoeng
dc.relation.ispartofBeilstein Journal of Organic Chemistryen
dc.rights© 2012 Martin et al; licensee Beilstein-Institut. This is an Open Access article under the terms of the Creative Commons Attribution License (http://creativecommons.org/licenses/by/2.0), which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. The license is subject to the Beilstein Journal of Organic Chemistry terms and conditions: (http://www.beilstein-journals.org/bjoc)en
dc.subjectC-H functionalizationen
dc.subjectDirect arylationen
dc.subjectHeterocyclesen
dc.subjectN-heterocyclicen
dc.subjectCarbenesen
dc.subjectPalladiumen
dc.subjectQD Chemistryen
dc.subject.lccQDen
dc.titleExtending the utility of [Pd(NHC)(cinnamyl)Cl] precatalysts : Direct arylation of heterocyclesen
dc.typeJournal articleen
dc.contributor.sponsorEPSRCen
dc.description.versionPublisher PDFen
dc.contributor.institutionUniversity of St Andrews. School of Chemistryen
dc.contributor.institutionUniversity of St Andrews. EaSTCHEMen
dc.identifier.doihttps://doi.org/10.3762/bjoc.8.187
dc.description.statusPeer revieweden
dc.identifier.grantnumberEP/J011053/1en


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