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Extending the utility of [Pd(NHC)(cinnamyl)Cl] precatalysts : Direct arylation of heterocycles
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dc.contributor.author | Martin, Anthony | |
dc.contributor.author | Chartoire, Anthony Raymond Georges | |
dc.contributor.author | Slawin, Alexandra Martha Zoya | |
dc.contributor.author | Nolan, Steven Patrick | |
dc.date.accessioned | 2012-11-20T16:31:02Z | |
dc.date.available | 2012-11-20T16:31:02Z | |
dc.date.issued | 2012-09-27 | |
dc.identifier | 30087527 | |
dc.identifier | 3794011c-ed1b-4b89-8c9c-9e3f721b15f1 | |
dc.identifier | 000309591800001 | |
dc.identifier | 84867219499 | |
dc.identifier.citation | Martin , A , Chartoire , A R G , Slawin , A M Z & Nolan , S P 2012 , ' Extending the utility of [Pd(NHC)(cinnamyl)Cl] precatalysts : Direct arylation of heterocycles ' , Beilstein Journal of Organic Chemistry , vol. 8 , pp. 1637-1643 . https://doi.org/10.3762/bjoc.8.187 | en |
dc.identifier.issn | 1860-5397 | |
dc.identifier.other | ORCID: /0000-0002-9527-6418/work/56861423 | |
dc.identifier.uri | https://hdl.handle.net/10023/3257 | |
dc.description.abstract | The use of [Pd(NHC)(cinnamyl)Cl] precatalysts in the direct arylation of heterocycles has been investigated. Among four different precatalysts, [Pd(SIPr)(cinnamyl)Cl] proved to be the most efficient promoter of the reaction. The C–H functionalization of sulfuror nitrogen-containing heterocycles has been achieved at low catalyst loadings. These catalyst charges range from 0.1 to 0.01 mol % palladium. | |
dc.format.extent | 7 | |
dc.format.extent | 427214 | |
dc.language.iso | eng | |
dc.relation.ispartof | Beilstein Journal of Organic Chemistry | en |
dc.subject | C-H functionalization | en |
dc.subject | Direct arylation | en |
dc.subject | Heterocycles | en |
dc.subject | N-heterocyclic | en |
dc.subject | Carbenes | en |
dc.subject | Palladium | en |
dc.subject | QD Chemistry | en |
dc.subject.lcc | QD | en |
dc.title | Extending the utility of [Pd(NHC)(cinnamyl)Cl] precatalysts : Direct arylation of heterocycles | en |
dc.type | Journal article | en |
dc.contributor.sponsor | EPSRC | en |
dc.contributor.institution | University of St Andrews. School of Chemistry | en |
dc.contributor.institution | University of St Andrews. EaSTCHEM | en |
dc.identifier.doi | https://doi.org/10.3762/bjoc.8.187 | |
dc.description.status | Peer reviewed | en |
dc.identifier.grantnumber | EP/J011053/1 | en |
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