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The role of silver additives in gold-mediated C-H functionalisation

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dc.contributor.authorPatrick, Scott R.
dc.contributor.authorBoogaerts, Ine I. F.
dc.contributor.authorGaillard, Sylvain
dc.contributor.authorSlawin, Alexandra M. Z.
dc.contributor.authorNolan, Steven P.
dc.date.accessioned2012-08-02T12:01:02Z
dc.date.available2012-08-02T12:01:02Z
dc.date.issued2011-07-01
dc.identifier.citationPatrick , S R , Boogaerts , I I F , Gaillard , S , Slawin , A M Z & Nolan , S P 2011 , ' The role of silver additives in gold-mediated C-H functionalisation ' , Beilstein Journal of Organic Chemistry , vol. 7 , pp. 892-896 . https://doi.org/10.3762/bjoc.7.102en
dc.identifier.issn1860-5397
dc.identifier.otherPURE: 16811575
dc.identifier.otherPURE UUID: c18817af-f063-4412-b7f0-6e27f2c5a1b0
dc.identifier.otherWOS: 000292282800001
dc.identifier.otherScopus: 79960405165
dc.identifier.otherORCID: /0000-0002-9527-6418/work/56861843
dc.identifier.urihttps://hdl.handle.net/10023/3035
dc.description.abstractThe role of silver additives is examined in the context of gold-mediated functionalisation of aromatic C-H bonds. Doubt is cast on the commonly cited route of halide abstraction from gold and evidence of substrate activation is given.
dc.format.extent5
dc.language.isoeng
dc.relation.ispartofBeilstein Journal of Organic Chemistryen
dc.rights© 2011 Patrick et al; licensee Beilstein-Institut. This is an Open Access article under the terms of the Creative Commons Attribution License (http://creativecommons.org/licenses/by/2.0), which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.en
dc.subjectC-H functionalisationen
dc.subjectGold catalysten
dc.subjectHalide abstractionen
dc.subjectN-heterocyclic carbeneen
dc.subjectSilver salten
dc.subjectSubstrate activationen
dc.subjectN-Heterocyclic carbenesen
dc.subjectBond formationen
dc.subjectCatalysisen
dc.subjectArylationen
dc.subjectComplexesen
dc.subjectAciden
dc.subjectQD Chemistryen
dc.subject.lccQDen
dc.titleThe role of silver additives in gold-mediated C-H functionalisationen
dc.typeJournal articleen
dc.contributor.sponsorEPSRCen
dc.contributor.sponsorEuropean Research Councilen
dc.description.versionPublisher PDFen
dc.contributor.institutionUniversity of St Andrews. School of Chemistryen
dc.contributor.institutionUniversity of St Andrews. EaSTCHEMen
dc.identifier.doihttps://doi.org/10.3762/bjoc.7.102
dc.description.statusPeer revieweden
dc.identifier.grantnumberEP/H015418/1en
dc.identifier.grantnumberFP7-227817 FUNCATen


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