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The role of silver additives in gold-mediated C-H functionalisation

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Patricketal2011BeilsteinJOrgChem7SilverAdditives.pdf (442.3Kb)
Date
01/07/2011
Author
Patrick, Scott R.
Boogaerts, Ine I. F.
Gaillard, Sylvain
Slawin, Alexandra M. Z.
Nolan, Steven P.
Keywords
C-H functionalisation
Gold catalyst
Halide abstraction
N-heterocyclic carbene
Silver salt
Substrate activation
N-Heterocyclic carbenes
Bond formation
Catalysis
Arylation
Complexes
Acid
QD Chemistry
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Abstract
The role of silver additives is examined in the context of gold-mediated functionalisation of aromatic C-H bonds. Doubt is cast on the commonly cited route of halide abstraction from gold and evidence of substrate activation is given.
Citation
Patrick , S R , Boogaerts , I I F , Gaillard , S , Slawin , A M Z & Nolan , S P 2011 , ' The role of silver additives in gold-mediated C-H functionalisation ' , Beilstein Journal of Organic Chemistry , vol. 7 , pp. 892-896 . https://doi.org/10.3762/bjoc.7.102
Publication
Beilstein Journal of Organic Chemistry
Status
Peer reviewed
DOI
https://doi.org/10.3762/bjoc.7.102
ISSN
1860-5397
Type
Journal article
Rights
© 2011 Patrick et al; licensee Beilstein-Institut. This is an Open Access article under the terms of the Creative Commons Attribution License (http://creativecommons.org/licenses/by/2.0), which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.
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  • University of St Andrews Research
URI
http://hdl.handle.net/10023/3035

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