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dc.contributor.authorTsiouri, Mantha
dc.contributor.authorSkorda, Konstantina
dc.contributor.authorPapadimitriou, Christos
dc.contributor.authorLi, Yang
dc.contributor.authorWoollins, J. Derek
dc.contributor.authorPlakatouras, John C.
dc.date.accessioned2012-07-31T08:31:02Z
dc.date.available2012-07-31T08:31:02Z
dc.date.issued2010
dc.identifier.citationTsiouri , M , Skorda , K , Papadimitriou , C , Li , Y , Woollins , J D & Plakatouras , J C 2010 , ' Interactions of trivalent lanthanide cations with a new hexadentate di-Schiff base : new lanthanide(III) complexes from (NE,N ' E)-2,2 '-(ethane-1,2-diylbis(oxy))bis(N-(pyridin-2-ylmethylene)ethanamine) ' , Bioinorganic Chemistry and Applications , vol. 2010 , 613140 . https://doi.org/10.1155/2010/613140en
dc.identifier.issn1565-3633
dc.identifier.otherPURE: 4638583
dc.identifier.otherPURE UUID: 34a499f0-2a9c-4c05-a69b-1ac21bcb39ec
dc.identifier.otherWOS: 000280796900001
dc.identifier.otherScopus: 77955394953
dc.identifier.otherORCID: /0000-0002-1498-9652/work/31779262
dc.identifier.urihttp://hdl.handle.net/10023/3034
dc.descriptionThis research was cofunded by the European Union in the framework of the program “Heraklitos” of the “Operational Program for Education and Initial Vocational Training” of the 3rd Community Support Framework of the Hellenic Ministry of Education, funded by 25% from national sources and by 75% from the European Social Fund (ESF).en
dc.description.abstractThe novel lanthanide(III) complexes [Ln(NO3)(2)L](NO3)center dot 3MeOH (Ln = La 1, Pr 2) and [Ln(NO3)(3)L](NO3)center dot 2MeOH (Ln = Gd 3, Yb 4), where L = (NE,N'E)-2,2'-(ethane-1,2-diylbis(oxy))bis(N-(pyridin-2-ylmethylene)ethanamine), have been obtained by direct reaction of the Schiff base ligand and the corresponding hydrated lanthanide(III) nitrates in methanol. All complexes were characterized spectroscopically and thermogravimetrically. Complex 4 was also characterized with crystallographic studies: orthorhombic P2(1)2(1)2(1), a = 10.6683(14), b = 13.4752(15), c = 19.3320(26) angstrom. In the molecular structure of 4, Yb(III) is surrounded by all donor atoms of the Schiff base (four nitrogen and two oxygen atoms) and four oxygen atoms belonging to two bidentate chelating nitrato ligands.
dc.format.extent7
dc.language.isoeng
dc.relation.ispartofBioinorganic Chemistry and Applicationsen
dc.rightsCopyright © 2010 Mantha Tsiouri et al. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.en
dc.subjectCrystal-structureen
dc.subjectMacrocyclic complexen
dc.subjectMetal-complexesen
dc.subjectLigandsen
dc.subjectEuropium(III)en
dc.subjectNeodymium(III)en
dc.subjectYttrium(III)en
dc.subjectLuminescenceen
dc.subjectCopper(III)en
dc.subjectNickel(II)en
dc.subjectQD Chemistryen
dc.subject.lccQDen
dc.titleInteractions of trivalent lanthanide cations with a new hexadentate di-Schiff base : new lanthanide(III) complexes from (NE,N ' E)-2,2 '-(ethane-1,2-diylbis(oxy))bis(N-(pyridin-2-ylmethylene)ethanamine)en
dc.typeJournal articleen
dc.description.versionPublisher PDFen
dc.contributor.institutionUniversity of St Andrews.School of Chemistryen
dc.contributor.institutionUniversity of St Andrews.EaSTCHEMen
dc.identifier.doihttps://doi.org/10.1155/2010/613140
dc.description.statusPeer revieweden


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