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Manganese catalysed enantioselective hydrogenation of in-situ-synthesised imines : efficient asymmetric synthesis of amino-indane derivatives

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dc.contributor.authorOates, Conor
dc.contributor.authorGoodfellow, Alister S.
dc.contributor.authorBuehl, Michael
dc.contributor.authorClarke, Matt
dc.date.accessioned2023-05-12T10:30:05Z
dc.date.available2023-05-12T10:30:05Z
dc.date.issued2023-05-21
dc.identifier285445045
dc.identifiercc66b591-d6e4-428f-bf4e-56ea0a44cace
dc.identifier85159342419
dc.identifier.citationOates , C , Goodfellow , A S , Buehl , M & Clarke , M 2023 , ' Manganese catalysed enantioselective hydrogenation of in-situ -synthesised imines : efficient asymmetric synthesis of amino-indane derivatives ' , Green Chemistry , vol. 25 , no. 10 , pp. 3864-3868 . https://doi.org/10.1039/D3GC00399Jen
dc.identifier.issn1463-9262
dc.identifier.otherORCID: /0000-0002-2444-1244/work/134491252
dc.identifier.otherORCID: /0000-0002-1095-7143/work/134491395
dc.identifier.urihttps://hdl.handle.net/10023/27597
dc.descriptionFunding: The authors would like to thank the University of St Andrews, and the EPSRC Centre for Doctoral Training in Critical Resource Catalysis (CRITICAT) for financial support [Ph.D. studentship to CO; Grant code: EP/L016419/1], and the EaSI-CAT programme PhD studentship to AG. They thank Solvias for the gift of chiral chemicals.en
dc.description.abstractA manganese catalyst of a facially coordinating P,N,N ligand catalyses the hydrogenation of imines derived from indanone derivatives with high enantioselectivity. There is no requirement for an activating group and imines can be generated in situ. The selectivity can be rationalised by DFT calculations.
dc.format.extent5
dc.format.extent584539
dc.language.isoeng
dc.relation.ispartofGreen Chemistryen
dc.subjectQD Chemistryen
dc.subjectDASen
dc.subjectMCCen
dc.subject.lccQDen
dc.titleManganese catalysed enantioselective hydrogenation of in-situ-synthesised imines : efficient asymmetric synthesis of amino-indane derivativesen
dc.typeJournal articleen
dc.contributor.sponsorEPSRCen
dc.contributor.institutionUniversity of St Andrews. School of Chemistryen
dc.contributor.institutionUniversity of St Andrews. EaSTCHEMen
dc.identifier.doi10.1039/D3GC00399J
dc.description.statusPeer revieweden
dc.identifier.grantnumberEP/L016419/1en


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