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Heteronuclear bimetallic complexes with 3d and 4f elements
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dc.contributor.author | Chalmers, Brian A. | |
dc.contributor.author | Cordes, David B. | |
dc.contributor.author | Bertram, Lauren | |
dc.contributor.author | Harraghy, Daniel J. | |
dc.contributor.author | Reid, Rachel C. | |
dc.contributor.author | Smellie, Iain A. | |
dc.contributor.author | Tarcza, Anna E. | |
dc.contributor.author | Thomson, Brodie J. | |
dc.date.accessioned | 2023-02-03T17:30:10Z | |
dc.date.available | 2023-02-03T17:30:10Z | |
dc.date.issued | 2023-02-03 | |
dc.identifier | 283227581 | |
dc.identifier | 1a3b1aac-33f3-4f4c-90ff-24cc3d636e2e | |
dc.identifier | 85152285496 | |
dc.identifier.citation | Chalmers , B A , Cordes , D B , Bertram , L , Harraghy , D J , Reid , R C , Smellie , I A , Tarcza , A E & Thomson , B J 2023 , ' Heteronuclear bimetallic complexes with 3 d and 4 f elements ' , Molbank , vol. 2023 , no. 1 , M1577 . https://doi.org/10.3390/M1577 | en |
dc.identifier.issn | 1422-8599 | |
dc.identifier.other | RIS: urn:F54F853AABA2A53BBC87FEB42CFFCA89 | |
dc.identifier.other | ORCID: /0000-0002-2999-2272/work/128096957 | |
dc.identifier.other | ORCID: /0000-0002-5366-9168/work/128097430 | |
dc.identifier.other | ORCID: /0000-0002-5829-6487/work/128097638 | |
dc.identifier.uri | https://hdl.handle.net/10023/26901 | |
dc.description.abstract | Three heteronuclear bimetallic complexes [Cu(MeOH)(L)Ln(NO3)3] ( 1-Ce ; Ln = Ce, 1-Pr ; Ln = Pr, and 1-Nd ; Ln = Nd) were prepared using H2L (1,3-bis[(3-methoxysalicylidene)amino]-2,2-dimethylpropane) in methanol, affording the complexes as green crystalline materials. These can be prepared in a one-pot synthesis from 2,2-dimethylpropan-1,3-diamine, o-vanillin, copper(II) nitrate, and Ln(III) nitrate (Ln = Ce, Pr, Nd). X-ray crystallography, high-resolution mass spectrometry, and UV-vis spectroscopy were used to characterize the bimetallic complexes. All three complexes showed the copper center adopting a five-coordinate square pyramidal geometry and the lanthanoid cation adopting a ten-coordinate geometry. | |
dc.format.extent | 9 | |
dc.format.extent | 1663526 | |
dc.language.iso | eng | |
dc.relation.ispartof | Molbank | en |
dc.subject | X-ray crystallography | en |
dc.subject | Bimetallic complexes | en |
dc.subject | UV-vis spectroscopy | en |
dc.subject | HRMS spectrometry | en |
dc.subject | QD Chemistry | en |
dc.subject | DAS | en |
dc.subject | MCC | en |
dc.subject.lcc | QD | en |
dc.title | Heteronuclear bimetallic complexes with 3d and 4f elements | en |
dc.type | Journal article | en |
dc.contributor.institution | University of St Andrews. School of Chemistry | en |
dc.contributor.institution | University of St Andrews. EaSTCHEM | en |
dc.identifier.doi | 10.3390/M1577 | |
dc.description.status | Peer reviewed | en |
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