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Direct Chan–Lam amination and etherification of aryl BMIDA reagents

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dc.contributor.authorHalford-McGuff, John
dc.contributor.authorIsrael, Eva Marie
dc.contributor.authorWest, Matthew
dc.contributor.authorVantourout, Julien Christian
dc.contributor.authorWatson, Allan J. B.
dc.date.accessioned2022-12-05T10:30:02Z
dc.date.available2022-12-05T10:30:02Z
dc.date.issued2022-12-06
dc.identifier281975599
dc.identifier1b98124e-93f6-4cd4-8681-46c92b28b613
dc.identifier85143690854
dc.identifier000894491600008
dc.identifier.citationHalford-McGuff , J , Israel , E M , West , M , Vantourout , J C & Watson , A J B 2022 , ' Direct Chan–Lam amination and etherification of aryl BMIDA reagents ' , European Journal of Organic Chemistry , vol. 2022 , no. 45 , e202200993 . https://doi.org/10.1002/ejoc.202200993en
dc.identifier.issn1434-193X
dc.identifier.otherORCID: /0000-0002-1582-4286/work/124490335
dc.identifier.urihttps://hdl.handle.net/10023/26541
dc.descriptionFunding: Engineering and Physical Sciences Research Council; University of St Andrews; Leverhulme Trust (GrantNumber(s): RF-2022-014).en
dc.description.abstractWe report the development of a method for the direct Chan–Lam coupling of arylboronic acid N-methyliminodiacetic acid esters (ArBMIDA) with amine and alcohol nucleophiles. A wide range of C–N and C–O cross-coupled products in 34–99% yield (34 examples). This method serves to expand the scope of organoboron components that can be used directly in this oxidative coupling reaction and provides opportunities for streamlining synthesis.
dc.format.extent4
dc.format.extent4725725
dc.language.isoeng
dc.relation.ispartofEuropean Journal of Organic Chemistryen
dc.subjectAminationen
dc.subjectBoronen
dc.subjectCopperen
dc.subjectCross-couplingen
dc.subjectEtherificationen
dc.subjectQD Chemistryen
dc.subjectDASen
dc.subjectMCCen
dc.subject.lccQDen
dc.titleDirect Chan–Lam amination and etherification of aryl BMIDA reagentsen
dc.typeJournal articleen
dc.contributor.sponsorThe Leverhulme Trusten
dc.contributor.sponsorIBioICen
dc.contributor.institutionUniversity of St Andrews. School of Chemistryen
dc.contributor.institutionUniversity of St Andrews. Sir James Mackenzie Institute for Early Diagnosisen
dc.identifier.doihttps://doi.org/10.1002/ejoc.202200993
dc.description.statusPeer revieweden
dc.identifier.grantnumberRF-2022-014en
dc.identifier.grantnumberen


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