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Unexpected triaxial preferences in some all-syn 1,3,5-trifluorocyclohexanes

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dc.contributor.authorYu, Cihang
dc.contributor.authorPiscelli, Bruno A.
dc.contributor.authorMaharik, Nawaf Al
dc.contributor.authorCordes, David B.
dc.contributor.authorSlawin, Alexandra M. Z.
dc.contributor.authorCormanich, Rodrigo A.
dc.contributor.authorO'Hagan, David
dc.date.accessioned2022-11-11T08:30:18Z
dc.date.available2022-11-11T08:30:18Z
dc.date.issued2022-11-28
dc.identifier.citationYu , C , Piscelli , B A , Maharik , N A , Cordes , D B , Slawin , A M Z , Cormanich , R A & O'Hagan , D 2022 , ' Unexpected triaxial preferences in some all- syn 1,3,5-trifluorocyclohexanes ' , Chemical Communications , vol. 58 , no. 92 , pp. 12855-12858 . https://doi.org/10.1039/D2CC05058Gen
dc.identifier.issn1359-7345
dc.identifier.otherPURE: 282093746
dc.identifier.otherPURE UUID: 44ce1bd4-79d4-4698-9786-30e9d968bfd7
dc.identifier.otherRIS: urn:DD985435E853FD6C47418D3700029DD2
dc.identifier.otherORCID: /0000-0002-0510-5552/work/122719764
dc.identifier.otherORCID: /0000-0002-9527-6418/work/122719962
dc.identifier.otherORCID: /0000-0002-5366-9168/work/122720083
dc.identifier.otherScopus: 85141760991
dc.identifier.otherWOS: 000877080800001
dc.identifier.urihttps://hdl.handle.net/10023/26374
dc.descriptionFunding: Authors thank the Chinese Scholarship Council and FAPESP for studentships (BAP, #2021/09716-5) a Young Researcher Award (RAC, #2018/03910-1) and FAEPEX for a fellowship (RAC, #2479/21).en
dc.description.abstractTheory and solution NMR indicate that all-syn 1,3,5-trifluorocyclohexane 5 adopts the expected tri-equatorial conformation, however in the solid state the more polar triaxial conformation is observed. This and the favoured conformations of substituted (Me, OMe, NH(CO)Me, NHBoc) derivatives of 5 are investigated to explore triaxial C–F preferences.
dc.format.extent4
dc.language.isoeng
dc.relation.ispartofChemical Communicationsen
dc.rightsCopyright © The Author(s) 2022. Open Access Article. This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.en
dc.subjectQD Chemistryen
dc.subjectDASen
dc.subjectMCCen
dc.subject.lccQDen
dc.titleUnexpected triaxial preferences in some all-syn 1,3,5-trifluorocyclohexanesen
dc.typeJournal articleen
dc.description.versionPublisher PDFen
dc.contributor.institutionUniversity of St Andrews. School of Chemistryen
dc.contributor.institutionUniversity of St Andrews. EaSTCHEMen
dc.contributor.institutionUniversity of St Andrews. Institute of Behavioural and Neural Sciencesen
dc.contributor.institutionUniversity of St Andrews. Biomedical Sciences Research Complexen
dc.identifier.doihttps://doi.org/10.1039/D2CC05058G
dc.description.statusPeer revieweden


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