Unexpected triaxial preferences in some all-syn 1,3,5-trifluorocyclohexanes

Thumbnail
View/Open
Yu_2022_CC_Unexpected_triaxial_CC.pdf (1.134Mb)
Date
28/11/2022
Author
Keywords
DAS
MCC
Metadata
Show full item record
Altmetrics Handle Statistics
Altmetrics DOI Statistics
Abstract
Theory and solution NMR indicate that all-syn 1,3,5-trifluorocyclohexane 5 adopts the expected tri-equatorial conformation, however in the solid state the more polar triaxial conformation is observed. This and the favoured conformations of substituted (Me, OMe, NH(CO)Me, NHBoc) derivatives of 5 are investigated to explore triaxial C–F preferences.
Citation
Yu , C , Piscelli , B A , Maharik , N A , Cordes , D B , Slawin , A M Z , Cormanich , R A & O'Hagan , D 2022 , ' Unexpected triaxial preferences in some all- syn 1,3,5-trifluorocyclohexanes ' , Chemical Communications , vol. 58 , no. 92 , pp. 12855-12858 . https://doi.org/10.1039/D2CC05058G
Publication
Chemical Communications
Status
Peer reviewed
DOI
https://doi.org/10.1039/D2CC05058G
ISSN
1359-7345
Type
Journal article
Rights
Copyright © The Author(s) 2022. Open Access Article. This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Description
Funding: Authors thank the Chinese Scholarship Council and FAPESP for studentships (BAP, #2021/09716-5) a Young Researcher Award (RAC, #2018/03910-1) and FAEPEX for a fellowship (RAC, #2479/21).
Collections
URI
http://hdl.handle.net/10023/26374

Items in the St Andrews Research Repository are protected by copyright, with all rights reserved, unless otherwise indicated.