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dc.contributor.authorAbdul Manan, Mohd Abdul Fatah
dc.contributor.authorCordes, David B.
dc.date.accessioned2022-11-09T16:30:14Z
dc.date.available2022-11-09T16:30:14Z
dc.date.issued2022-09-15
dc.identifier.citationAbdul Manan , M A F & Cordes , D B 2022 , ' Cadmium(II) Schiff base complex containing 5-fluoroisatin moiety : synthesis, characterization, antibacterial activity and structural studies ' , Trends in Sciences , vol. 19 , no. 18 , 5796 . https://doi.org/10.48048/tis.2022.5796en
dc.identifier.issn2774-0226
dc.identifier.otherPURE: 275346009
dc.identifier.otherPURE UUID: 53b404e3-b8b7-41ec-9b53-cd0e6789d0e2
dc.identifier.otherORCID: /0000-0002-5366-9168/work/122720082
dc.identifier.otherScopus: 85138139990
dc.identifier.urihttp://hdl.handle.net/10023/26348
dc.descriptionFunding: Financial support is acknowledged from Universiti Teknologi MARA.en
dc.description.abstractThe Schiff base ligand, HSB5FISA ( H1 ), obtained by the condensation of S-benzyldithiocarbazate with 5-fluoroisatin, has been employed to synthesize a new cadmium(II) complex, Cd(SB5FISA)2 ( 2 ) (SB5FISA = monoanionic form of H1 ). The complex has been characterized by elemental analysis, molar conductivity, magnetic susceptibility, inductively coupled plasma atomic emission spectroscopy (ICP-AES), Fourier-transform infrared spectroscopy (FT-IR) and ultraviolet-visible spectroscopy (UV-Vis). The crystallographic study of Cd(SB5FISA)2•2DMSO ( 2a ) (DMSO = dimethyl sulfoxide) was conducted using single-crystal X-ray diffraction. The crystal structure of 2a confirmed the presence of six-coordinated cadmium in a distorted octahedral environment. Ligand H1 behaves in a tridentate monoanionic fashion, coordinating to a cadmium(II) metal centre through the thiolate sulfur, azomethine nitrogen and carbonyl oxygen. The antibacterial activity of both H1 and 2 was examined against four different bacterial strains using the disc diffusion method. Complex 2 showed significant inhibitory effect against Bacillus subtilis with an inhibition zone of 14 mm, comparable to the standard antibiotic streptomycin.
dc.format.extent8
dc.language.isoeng
dc.relation.ispartofTrends in Sciencesen
dc.rightsCopyright © 2022 TiS. Open Access. This work is licensed under a Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International License (https://creativecommons.org/licenses/by-nc-nd/4.0/).en
dc.subjectCadmium(II)en
dc.subjectDithiocarbazateen
dc.subject5-fluoroisatinen
dc.subjectSingle-crystal structureen
dc.subjectAntibacterialen
dc.subjectQD Chemistryen
dc.subjectQR Microbiologyen
dc.subjectDASen
dc.subjectMCCen
dc.subject.lccQDen
dc.subject.lccQRen
dc.titleCadmium(II) Schiff base complex containing 5-fluoroisatin moiety : synthesis, characterization, antibacterial activity and structural studiesen
dc.typeJournal articleen
dc.description.versionPublisher PDFen
dc.contributor.institutionUniversity of St Andrews. School of Chemistryen
dc.contributor.institutionUniversity of St Andrews. EaSTCHEMen
dc.identifier.doihttps://doi.org/10.48048/tis.2022.5796
dc.description.statusPeer revieweden


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