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dc.contributor.authorLi, Teng
dc.contributor.authorLightfoot, Philip
dc.identifier.citationLi , T & Lightfoot , P 2022 , ' Layered hybrid iron fluorides ' , Crystals , vol. 12 , no. 10 , 1443 .
dc.identifier.otherPURE: 281675066
dc.identifier.otherPURE UUID: c8f78122-6bcc-45d6-8334-881f6d5f292c
dc.identifier.otherORCID: /0000-0001-7048-3982/work/120849827
dc.identifier.otherScopus: 85140929989
dc.identifier.otherWOS: 000872492300001
dc.descriptionFunding: We thank the China Scholarship Council and the University of St Andrews for a PhD studentship to T.L. (201606280032) and the China Postdoctoral Science Foundation (2022M710619).en
dc.description.abstractThe first examples of layered hybrid iron fluorides are reported. In the reactions carried out, the chain compound (H2pipz)FeF5·H2O always occurs as the major phase, with the layered compounds, (H2pipz)3Fe4F18·2H2O and (H2pipz)2Fe3F13·H2O, being isolated from some reactions as major impurities. The latter two compounds feature two-dimensional sheets of corner-and edge-shared FeIIIF6 octahedra, resulting in two distinct layer architectures. The compound (H2pipz)FeF5·H2O, isolated as the major phase, crystallises with a one-dimensional structure exhibiting zig-zag [FeF5]∞ chains. This work opens up the potential for a much wider family of layered hybrid transition-metal fluorides.
dc.rightsCopyright: © 2022 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://
dc.subjectIron fluoridesen
dc.subjectHybrid compoundsen
dc.subjectCrystal structureen
dc.subjectQD Chemistryen
dc.titleLayered hybrid iron fluoridesen
dc.typeJournal articleen
dc.description.versionPublisher PDFen
dc.contributor.institutionUniversity of St Andrews. EaSTCHEMen
dc.contributor.institutionUniversity of St Andrews. School of Chemistryen
dc.description.statusPeer revieweden

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