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Layered hybrid iron fluorides
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dc.contributor.author | Li, Teng | |
dc.contributor.author | Lightfoot, Philip | |
dc.date.accessioned | 2022-10-13T10:30:02Z | |
dc.date.available | 2022-10-13T10:30:02Z | |
dc.date.issued | 2022-10-13 | |
dc.identifier.citation | Li , T & Lightfoot , P 2022 , ' Layered hybrid iron fluorides ' , Crystals , vol. 12 , no. 10 , 1443 . https://doi.org/10.3390/cryst12101443 | en |
dc.identifier.issn | 2073-4352 | |
dc.identifier.other | PURE: 281675066 | |
dc.identifier.other | PURE UUID: c8f78122-6bcc-45d6-8334-881f6d5f292c | |
dc.identifier.other | ORCID: /0000-0001-7048-3982/work/120849827 | |
dc.identifier.other | Scopus: 85140929989 | |
dc.identifier.other | WOS: 000872492300001 | |
dc.identifier.uri | https://hdl.handle.net/10023/26189 | |
dc.description | Funding: We thank the China Scholarship Council and the University of St Andrews for a PhD studentship to T.L. (201606280032) and the China Postdoctoral Science Foundation (2022M710619). | en |
dc.description.abstract | The first examples of layered hybrid iron fluorides are reported. In the reactions carried out, the chain compound (H2pipz)FeF5·H2O always occurs as the major phase, with the layered compounds, (H2pipz)3Fe4F18·2H2O and (H2pipz)2Fe3F13·H2O, being isolated from some reactions as major impurities. The latter two compounds feature two-dimensional sheets of corner-and edge-shared FeIIIF6 octahedra, resulting in two distinct layer architectures. The compound (H2pipz)FeF5·H2O, isolated as the major phase, crystallises with a one-dimensional structure exhibiting zig-zag [FeF5]∞ chains. This work opens up the potential for a much wider family of layered hybrid transition-metal fluorides. | |
dc.format.extent | 9 | |
dc.language.iso | eng | |
dc.relation.ispartof | Crystals | en |
dc.rights | Copyright: © 2022 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https:// creativecommons.org/licenses/by/4.0/). | en |
dc.subject | Iron fluorides | en |
dc.subject | Hybrid compounds | en |
dc.subject | Crystal structure | en |
dc.subject | QD Chemistry | en |
dc.subject | DAS | en |
dc.subject | MCC | en |
dc.subject.lcc | QD | en |
dc.title | Layered hybrid iron fluorides | en |
dc.type | Journal article | en |
dc.description.version | Publisher PDF | en |
dc.contributor.institution | University of St Andrews. EaSTCHEM | en |
dc.contributor.institution | University of St Andrews. School of Chemistry | en |
dc.identifier.doi | https://doi.org/10.3390/cryst12101443 | |
dc.description.status | Peer reviewed | en |
dc.identifier.url | https://www.mdpi.com/2073-4352/12/10/1443 | en |
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