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Layered hybrid iron fluorides

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Li_2022_Layered_hybrid_iron_fluorides_Crystals_12_10_01443_CCBY.pdf (3.265Mb)
Date
13/10/2022
Author
Li, Teng
Lightfoot, Philip
Keywords
Iron fluorides
Hybrid compounds
Crystal structure
QD Chemistry
DAS
MCC
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Abstract
The first examples of layered hybrid iron fluorides are reported. In the reactions carried out, the chain compound (H2pipz)FeF5·H2O always occurs as the major phase, with the layered compounds, (H2pipz)3Fe4F18·2H2O and (H2pipz)2Fe3F13·H2O, being isolated from some reactions as major impurities. The latter two compounds feature two-dimensional sheets of corner-and edge-shared FeIIIF6 octahedra, resulting in two distinct layer architectures. The compound (H2pipz)FeF5·H2O, isolated as the major phase, crystallises with a one-dimensional structure exhibiting zig-zag [FeF5]∞ chains. This work opens up the potential for a much wider family of layered hybrid transition-metal fluorides.
Citation
Li , T & Lightfoot , P 2022 , ' Layered hybrid iron fluorides ' , Crystals , vol. 12 , no. 10 , 1443 . https://doi.org/10.3390/cryst12101443
Publication
Crystals
Status
Peer reviewed
DOI
https://doi.org/10.3390/cryst12101443
ISSN
2073-4352
Type
Journal article
Rights
Copyright: © 2022 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https:// creativecommons.org/licenses/by/4.0/).
Description
Funding: We thank the China Scholarship Council and the University of St Andrews for a PhD studentship to T.L. (201606280032) and the China Postdoctoral Science Foundation (2022M710619).
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  • University of St Andrews Research
URL
https://www.mdpi.com/2073-4352/12/10/1443
URI
http://hdl.handle.net/10023/26189

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