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A luminescent 1D silver polymer containing [2.2]paracyclophane ligands
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dc.contributor.author | Mackenzie, Campbell F. R. | |
dc.contributor.author | Delforce, Lucie | |
dc.contributor.author | Rota Martir, D. | |
dc.contributor.author | Cordes, David B. | |
dc.contributor.author | Slawin, Alexandra M. Z. | |
dc.contributor.author | Zysman-Colman, Eli | |
dc.date.accessioned | 2021-08-02T08:30:18Z | |
dc.date.available | 2021-08-02T08:30:18Z | |
dc.date.issued | 2021-08-02 | |
dc.identifier.citation | Mackenzie , C F R , Delforce , L , Rota Martir , D , Cordes , D B , Slawin , A M Z & Zysman-Colman , E 2021 , ' A luminescent 1D silver polymer containing [2.2]paracyclophane ligands ' , Frontiers in Chemistry , vol. 9 , 728845 . https://doi.org/10.3389/fchem.2021.728845 | en |
dc.identifier.issn | 2296-2646 | |
dc.identifier.other | PURE: 275025561 | |
dc.identifier.other | PURE UUID: daa8fc26-c08b-42a9-8054-b950d65a7d3b | |
dc.identifier.other | ORCID: /0000-0002-9527-6418/work/98196628 | |
dc.identifier.other | ORCID: /0000-0002-5366-9168/work/98196683 | |
dc.identifier.other | ORCID: /0000-0001-7183-6022/work/98197041 | |
dc.identifier.other | Scopus: 85113144122 | |
dc.identifier.other | WOS: 000687379200001 | |
dc.identifier.uri | https://hdl.handle.net/10023/23691 | |
dc.description | Funding: UK EPSRC Grant Number(s) EP/P014082/1, EP/M02105X/1, EP/R035164/1). | en |
dc.description.abstract | [2.2]Paracyclophane scaffolds have seen limited use as building blocks in supramolecular chemistry. Here, we report the synthesis and characterization of a 1D coordination polymer consisting of silver(I) ions bound to a [2.2]paracyclophane scaffold functionalized with two 4-pyridyl units. The structure of the polymer has been determined from single crystal X-ray diffraction analysis and reveals two different silver coordination motifs that alternate along the 1D coordination polymer. The coordination polymer exhibits strong blue and sky-blue fluorescence in solution and in the crystalline solid state, respectively. | |
dc.format.extent | 6 | |
dc.language.iso | eng | |
dc.relation.ispartof | Frontiers in Chemistry | en |
dc.rights | Copyright © 2021 Mackenzie, Delforce, Rota Martir, Cordes, Slawin and Zysman-Colman. This is an open-access article distributed under the terms of the Creative Commons Attribution License (CC BY). The use, distribution or reproduction in other forums is permitted, provided the original author(s) and the copyright owner(s) are credited and that the original publication in this journal is cited, in accordance with accepted academic practice. No use, distribution or reproduction is permitted which does not comply with these terms. | en |
dc.subject | Coordination polymer | en |
dc.subject | Cyclophane | en |
dc.subject | Supramolecular chemistry | en |
dc.subject | Silver | en |
dc.subject | QD Chemistry | en |
dc.subject | DAS | en |
dc.subject.lcc | QD | en |
dc.title | A luminescent 1D silver polymer containing [2.2]paracyclophane ligands | en |
dc.type | Journal article | en |
dc.contributor.sponsor | EPSRC | en |
dc.contributor.sponsor | EPSRC | en |
dc.description.version | Publisher PDF | en |
dc.contributor.institution | University of St Andrews. School of Chemistry | en |
dc.contributor.institution | University of St Andrews. EaSTCHEM | en |
dc.identifier.doi | https://doi.org/10.3389/fchem.2021.728845 | |
dc.description.status | Peer reviewed | en |
dc.identifier.grantnumber | EP/M02105X/1 | en |
dc.identifier.grantnumber | EP/R035164/1 | en |
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