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dc.contributor.authorMackenzie, Campbell F. R.
dc.contributor.authorDelforce, Lucie
dc.contributor.authorRota Martir, D.
dc.contributor.authorCordes, David B.
dc.contributor.authorSlawin, Alexandra M. Z.
dc.contributor.authorZysman-Colman, Eli
dc.date.accessioned2021-08-02T08:30:18Z
dc.date.available2021-08-02T08:30:18Z
dc.date.issued2021-08-02
dc.identifier.citationMackenzie , C F R , Delforce , L , Rota Martir , D , Cordes , D B , Slawin , A M Z & Zysman-Colman , E 2021 , ' A luminescent 1D silver polymer containing [2.2]paracyclophane ligands ' , Frontiers in Chemistry , vol. 9 , 728845 . https://doi.org/10.3389/fchem.2021.728845en
dc.identifier.issn2296-2646
dc.identifier.otherPURE: 275025561
dc.identifier.otherPURE UUID: daa8fc26-c08b-42a9-8054-b950d65a7d3b
dc.identifier.otherORCID: /0000-0002-9527-6418/work/98196628
dc.identifier.otherORCID: /0000-0002-5366-9168/work/98196683
dc.identifier.otherORCID: /0000-0001-7183-6022/work/98197041
dc.identifier.otherScopus: 85113144122
dc.identifier.otherWOS: 000687379200001
dc.identifier.urihttp://hdl.handle.net/10023/23691
dc.descriptionFunding: UK EPSRC Grant Number(s) EP/P014082/1, EP/M02105X/1, EP/R035164/1).en
dc.description.abstract[2.2]Paracyclophane scaffolds have seen limited use as building blocks in supramolecular chemistry. Here, we report the synthesis and characterization of a 1D coordination polymer consisting of silver(I) ions bound to a [2.2]paracyclophane scaffold functionalized with two 4-pyridyl units. The structure of the polymer has been determined from single crystal X-ray diffraction analysis and reveals two different silver coordination motifs that alternate along the 1D coordination polymer. The coordination polymer exhibits strong blue and sky-blue fluorescence in solution and in the crystalline solid state, respectively.
dc.format.extent6
dc.language.isoeng
dc.relation.ispartofFrontiers in Chemistryen
dc.rightsCopyright © 2021 Mackenzie, Delforce, Rota Martir, Cordes, Slawin and Zysman-Colman. This is an open-access article distributed under the terms of the Creative Commons Attribution License (CC BY). The use, distribution or reproduction in other forums is permitted, provided the original author(s) and the copyright owner(s) are credited and that the original publication in this journal is cited, in accordance with accepted academic practice. No use, distribution or reproduction is permitted which does not comply with these terms.en
dc.subjectCoordination polymeren
dc.subjectCyclophaneen
dc.subjectSupramolecular chemistryen
dc.subjectSilveren
dc.subjectQD Chemistryen
dc.subjectDASen
dc.subject.lccQDen
dc.titleA luminescent 1D silver polymer containing [2.2]paracyclophane ligandsen
dc.typeJournal articleen
dc.description.versionPublisher PDFen
dc.contributor.institutionUniversity of St Andrews.School of Chemistryen
dc.contributor.institutionUniversity of St Andrews.EaSTCHEMen
dc.identifier.doihttps://doi.org/10.3389/fchem.2021.728845
dc.description.statusPeer revieweden


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