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A luminescent 1D silver polymer containing [2.2]paracyclophane ligands
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dc.contributor.author | Mackenzie, Campbell F. R. | |
dc.contributor.author | Delforce, Lucie | |
dc.contributor.author | Rota Martir, D. | |
dc.contributor.author | Cordes, David B. | |
dc.contributor.author | Slawin, Alexandra M. Z. | |
dc.contributor.author | Zysman-Colman, Eli | |
dc.date.accessioned | 2021-08-02T08:30:18Z | |
dc.date.available | 2021-08-02T08:30:18Z | |
dc.date.issued | 2021-08-02 | |
dc.identifier | 275025561 | |
dc.identifier | daa8fc26-c08b-42a9-8054-b950d65a7d3b | |
dc.identifier | 85113144122 | |
dc.identifier | 000687379200001 | |
dc.identifier.citation | Mackenzie , C F R , Delforce , L , Rota Martir , D , Cordes , D B , Slawin , A M Z & Zysman-Colman , E 2021 , ' A luminescent 1D silver polymer containing [2.2]paracyclophane ligands ' , Frontiers in Chemistry , vol. 9 , 728845 . https://doi.org/10.3389/fchem.2021.728845 | en |
dc.identifier.issn | 2296-2646 | |
dc.identifier.other | ORCID: /0000-0002-9527-6418/work/98196628 | |
dc.identifier.other | ORCID: /0000-0002-5366-9168/work/98196683 | |
dc.identifier.other | ORCID: /0000-0001-7183-6022/work/98197041 | |
dc.identifier.uri | https://hdl.handle.net/10023/23691 | |
dc.description | Funding: UK EPSRC Grant Number(s) EP/P014082/1, EP/M02105X/1, EP/R035164/1). | en |
dc.description.abstract | [2.2]Paracyclophane scaffolds have seen limited use as building blocks in supramolecular chemistry. Here, we report the synthesis and characterization of a 1D coordination polymer consisting of silver(I) ions bound to a [2.2]paracyclophane scaffold functionalized with two 4-pyridyl units. The structure of the polymer has been determined from single crystal X-ray diffraction analysis and reveals two different silver coordination motifs that alternate along the 1D coordination polymer. The coordination polymer exhibits strong blue and sky-blue fluorescence in solution and in the crystalline solid state, respectively. | |
dc.format.extent | 6 | |
dc.format.extent | 1271972 | |
dc.language.iso | eng | |
dc.relation.ispartof | Frontiers in Chemistry | en |
dc.subject | Coordination polymer | en |
dc.subject | Cyclophane | en |
dc.subject | Supramolecular chemistry | en |
dc.subject | Silver | en |
dc.subject | QD Chemistry | en |
dc.subject | DAS | en |
dc.subject.lcc | QD | en |
dc.title | A luminescent 1D silver polymer containing [2.2]paracyclophane ligands | en |
dc.type | Journal article | en |
dc.contributor.sponsor | EPSRC | en |
dc.contributor.sponsor | EPSRC | en |
dc.contributor.institution | University of St Andrews. School of Chemistry | en |
dc.contributor.institution | University of St Andrews. EaSTCHEM | en |
dc.identifier.doi | https://doi.org/10.3389/fchem.2021.728845 | |
dc.description.status | Peer reviewed | en |
dc.identifier.grantnumber | EP/M02105X/1 | en |
dc.identifier.grantnumber | EP/R035164/1 | en |
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