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A luminescent 1D silver polymer containing [2.2]paracyclophane ligands

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Date
02/08/2021
Author
Mackenzie, Campbell F. R.
Delforce, Lucie
Rota Martir, D.
Cordes, David B.
Slawin, Alexandra M. Z.
Zysman-Colman, Eli
Keywords
Coordination polymer
Cyclophane
Supramolecular chemistry
Silver
QD Chemistry
DAS
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Abstract
[2.2]Paracyclophane scaffolds have seen limited use as building blocks in supramolecular chemistry. Here, we report the synthesis and characterization of a 1D coordination polymer consisting of silver(I) ions bound to a [2.2]paracyclophane scaffold functionalized with two 4-pyridyl units. The structure of the polymer has been determined from single crystal X-ray diffraction analysis and reveals two different silver coordination motifs that alternate along the 1D coordination polymer. The coordination polymer exhibits strong blue and sky-blue fluorescence in solution and in the crystalline solid state, respectively.
Citation
Mackenzie , C F R , Delforce , L , Rota Martir , D , Cordes , D B , Slawin , A M Z & Zysman-Colman , E 2021 , ' A luminescent 1D silver polymer containing [2.2]paracyclophane ligands ' , Frontiers in Chemistry , vol. 9 , 728845 . https://doi.org/10.3389/fchem.2021.728845
Publication
Frontiers in Chemistry
Status
Peer reviewed
DOI
https://doi.org/10.3389/fchem.2021.728845
ISSN
2296-2646
Type
Journal article
Rights
Copyright © 2021 Mackenzie, Delforce, Rota Martir, Cordes, Slawin and Zysman-Colman. This is an open-access article distributed under the terms of the Creative Commons Attribution License (CC BY). The use, distribution or reproduction in other forums is permitted, provided the original author(s) and the copyright owner(s) are credited and that the original publication in this journal is cited, in accordance with accepted academic practice. No use, distribution or reproduction is permitted which does not comply with these terms.
Description
Funding: UK EPSRC Grant Number(s) EP/P014082/1, EP/M02105X/1, EP/R035164/1).
Collections
  • University of St Andrews Research
URI
http://hdl.handle.net/10023/23691

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