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Reactivity of Woollins’ Reagent toward 2-en-1-imines (Schiff bases) : a facile approach to synthesize new selenium-phosphorus-nitrogen heterocycles

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dc.contributor.authorHua, Guoxiong
dc.contributor.authorCordes, David B
dc.contributor.authorSlawin, Alexandra
dc.contributor.authorWoollins, J. Derek
dc.date.accessioned2020-11-04T00:38:52Z
dc.date.available2020-11-04T00:38:52Z
dc.date.issued2019-11-24
dc.identifier262322378
dc.identifier57d0fb4a-df18-4a94-bf68-5d1d7de66e81
dc.identifier85074784115
dc.identifier000493848900001
dc.identifier.citationHua , G , Cordes , D B , Slawin , A & Woollins , J D 2019 , ' Reactivity of Woollins’ Reagent toward 2-en-1-imines (Schiff bases) : a facile approach to synthesize new selenium-phosphorus-nitrogen heterocycles ' , European Journal of Inorganic Chemistry , vol. 2019 , no. 43 , pp. 4682-4689 . https://doi.org/10.1002/ejic.201901030en
dc.identifier.issn1434-1948
dc.identifier.otherRIS: urn:FDC948188117B44269E21DAA25E2E14E
dc.identifier.otherORCID: /0000-0002-9527-6418/work/64360871
dc.identifier.otherORCID: /0000-0002-1498-9652/work/64360899
dc.identifier.otherORCID: /0000-0002-5366-9168/work/64361042
dc.identifier.urihttps://hdl.handle.net/10023/20894
dc.descriptionAuthors are grateful to the University of St Andrews for financial support and the EPSRC National Mass Spectrometry Service Centre (Swansea) for mass spectral measurements.en
dc.description.abstractWoollins’ Reagent serves as a reductive cycloaddition reagent, reacting with 2‐en‐1‐imines containing a conjugated C=C bond group (Schiff bases) leading to a series of four‐, five‐, six‐membered 1,2‐azaphospholidines incorporating one or two N‐P=Se linkages. Ten single crystal X‐ray structures confirming the formation of these small N‐P‐Se heterocycles are reported.
dc.format.extent1783994
dc.language.isoeng
dc.relation.ispartofEuropean Journal of Inorganic Chemistryen
dc.subjectSeleniumen
dc.subjectWoollins’ Reagenten
dc.subjectSynthesisen
dc.subjectPhosphorus-selenium-nitrogen hetrocyclesen
dc.subjectX-ray structureen
dc.subjectQD Chemistryen
dc.subjectDASen
dc.subject.lccQDen
dc.titleReactivity of Woollins’ Reagent toward 2-en-1-imines (Schiff bases) : a facile approach to synthesize new selenium-phosphorus-nitrogen heterocyclesen
dc.typeJournal articleen
dc.contributor.institutionUniversity of St Andrews. School of Chemistryen
dc.contributor.institutionUniversity of St Andrews. EaSTCHEMen
dc.identifier.doi10.1002/ejic.201901030
dc.description.statusPeer revieweden
dc.date.embargoedUntil2020-11-04


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