Reactivity of Woollins’ Reagent toward 2-en-1-imines (Schiff bases) : a facile approach to synthesize new selenium-phosphorus-nitrogen heterocycles
Abstract
Woollins’ Reagent serves as a reductive cycloaddition reagent, reacting with 2‐en‐1‐imines containing a conjugated C=C bond group (Schiff bases) leading to a series of four‐, five‐, six‐membered 1,2‐azaphospholidines incorporating one or two N‐P=Se linkages. Ten single crystal X‐ray structures confirming the formation of these small N‐P‐Se heterocycles are reported.
Citation
Hua , G , Cordes , D B , Slawin , A & Woollins , J D 2019 , ' Reactivity of Woollins’ Reagent toward 2-en-1-imines (Schiff bases) : a facile approach to synthesize new selenium-phosphorus-nitrogen heterocycles ' , European Journal of Inorganic Chemistry , vol. 2019 , no. 43 , pp. 4682-4689 . https://doi.org/10.1002/ejic.201901030
Publication
European Journal of Inorganic Chemistry
Status
Peer reviewed
ISSN
1434-1948Type
Journal article
Rights
Copyright © 2019 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim. This work has been made available online in accordance with publisher policies or with permission. Permission for further reuse of this content should be sought from the publisher or the rights holder. This is the author created accepted manuscript following peer review and may differ slightly from the final published version. The final published version of this work is available at https://doi.org/10.1002/ejic.201901030
Description
Authors are grateful to the University of St Andrews for financial support and the EPSRC National Mass Spectrometry Service Centre (Swansea) for mass spectral measurements.Collections
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