Reactivity of Woollins’ Reagent toward 2-en-1-imines (Schiff bases) : a facile approach to synthesize new selenium-phosphorus-nitrogen heterocycles
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Woollins’ Reagent serves as a reductive cycloaddition reagent, reacting with 2‐en‐1‐imines containing a conjugated C=C bond group (Schiff bases) leading to a series of four‐, five‐, six‐membered 1,2‐azaphospholidines incorporating one or two N‐P=Se linkages. Ten single crystal X‐ray structures confirming the formation of these small N‐P‐Se heterocycles are reported.
Hua , G , Cordes , D B , Slawin , A & Woollins , J D 2019 , ' Reactivity of Woollins’ Reagent toward 2-en-1-imines (Schiff bases) : a facile approach to synthesize new selenium-phosphorus-nitrogen heterocycles ' , European Journal of Inorganic Chemistry , vol. 2019 , no. 43 , pp. 4682-4689 . https://doi.org/10.1002/ejic.201901030
European Journal of Inorganic Chemistry
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DescriptionAuthors are grateful to the University of St Andrews for financial support and the EPSRC National Mass Spectrometry Service Centre (Swansea) for mass spectral measurements.
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