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A Pd3L6 supramolecular cage incorporating photoactive [2.2]paracyclophane Units
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dc.contributor.author | Rota Martir, Diego | |
dc.contributor.author | Delforce, Lucie | |
dc.contributor.author | Cordes, David B. | |
dc.contributor.author | Slawin, Alexandra M. Z. | |
dc.contributor.author | Warriner, Stuart | |
dc.contributor.author | Jacquemin, Denis | |
dc.contributor.author | Zysman-Colman, Eli | |
dc.date.accessioned | 2020-11-01T00:38:28Z | |
dc.date.available | 2020-11-01T00:38:28Z | |
dc.date.issued | 2019-11-01 | |
dc.identifier.citation | Rota Martir , D , Delforce , L , Cordes , D B , Slawin , A M Z , Warriner , S , Jacquemin , D & Zysman-Colman , E 2019 , ' A Pd 3 L 6 supramolecular cage incorporating photoactive [2.2]paracyclophane Units ' , Inorganic Chemistry Frontiers , vol. Advance Article . https://doi.org/10.1039/C9QI01147A | en |
dc.identifier.issn | 2052-1553 | |
dc.identifier.other | PURE: 262929568 | |
dc.identifier.other | PURE UUID: a6ef272c-9260-42e8-b710-66b1ea8c824b | |
dc.identifier.other | ORCID: /0000-0002-9527-6418/work/64697455 | |
dc.identifier.other | ORCID: /0000-0002-5366-9168/work/64697469 | |
dc.identifier.other | ORCID: /0000-0001-7183-6022/work/64697942 | |
dc.identifier.other | Scopus: 85077036371 | |
dc.identifier.other | WOS: 000503509100021 | |
dc.identifier.uri | https://hdl.handle.net/10023/20867 | |
dc.description | EZ-C acknowledges the University of St Andrews and EPSRC (EP/M02105X/1) for financial support. We thank the EPSRC UK National Mass Spectrometry Facility at Swansea University for analytical services. We thank Umicore AG for the gift of materials. | en |
dc.description.abstract | [2.2]Paracyclophane (pCp) scaffolds, unlike many -conjugated building blocks, have been rarely explored in supramolecular self-assembly. Herein we report the synthesis and characterization of two ligands, pCpd3py and pCpd4py , composed of a pCp core functionalized at its 7- and 15-positions respectively with 3-pyridyl and 4-pyridyl units. The self-assembly of pCpd4py with Pd2+ metal ions afforded a [Pd3( pCpd4py )6]6+ cage structure, pCpd4py-Pd , where the six pCpd4py ligands doubly bridge each edge of the Pd3 triangular core. The ligand pCpd4py and the palladium cage pCpd4py-Pd have been characterized by NMR spectroscopy, ESI-MS spectrometry and X-ray diffraction analyses and their photophysical properties investigated by steady-state and time-resolved emission spectroscopy as well as Time-Dependent Density Functional Theory calculations. | |
dc.language.iso | eng | |
dc.relation.ispartof | Inorganic Chemistry Frontiers | en |
dc.rights | Copyright © 2019 The Author(s). This work has been made available online in accordance with publisher policies or with permission. Permission for further reuse of this content should be sought from the publisher or the rights holder. This is the author created accepted manuscript following peer review and may differ slightly from the final published version. The final published version of this work is available at https://doi.org/10.1039/C9QI01147A | en |
dc.subject | Luminescent palladium cage | en |
dc.subject | [2.2]paracyclophane ligands | en |
dc.subject | Supramolecular assembly | en |
dc.subject | QD Chemistry | en |
dc.subject | DAS | en |
dc.subject.lcc | QD | en |
dc.title | A Pd3L6 supramolecular cage incorporating photoactive [2.2]paracyclophane Units | en |
dc.type | Journal article | en |
dc.contributor.sponsor | EPSRC | en |
dc.description.version | Postprint | en |
dc.contributor.institution | University of St Andrews. Organic Semiconductor Centre | en |
dc.contributor.institution | University of St Andrews. School of Chemistry | en |
dc.contributor.institution | University of St Andrews. EaSTCHEM | en |
dc.identifier.doi | https://doi.org/10.1039/C9QI01147A | |
dc.description.status | Peer reviewed | en |
dc.date.embargoedUntil | 2020-11-01 | |
dc.identifier.grantnumber | EP/M02105X/1 | en |
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