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dc.contributor.authorRota Martir, Diego
dc.contributor.authorDelforce, Lucie
dc.contributor.authorCordes, David B.
dc.contributor.authorSlawin, Alexandra M. Z.
dc.contributor.authorWarriner, Stuart
dc.contributor.authorJacquemin, Denis
dc.contributor.authorZysman-Colman, Eli
dc.date.accessioned2020-11-01T00:38:28Z
dc.date.available2020-11-01T00:38:28Z
dc.date.issued2019-11-01
dc.identifier262929568
dc.identifiera6ef272c-9260-42e8-b710-66b1ea8c824b
dc.identifier85077036371
dc.identifier000503509100021
dc.identifier.citationRota Martir , D , Delforce , L , Cordes , D B , Slawin , A M Z , Warriner , S , Jacquemin , D & Zysman-Colman , E 2019 , ' A Pd 3 L 6 supramolecular cage incorporating photoactive [2.2]paracyclophane Units ' , Inorganic Chemistry Frontiers , vol. Advance Article . https://doi.org/10.1039/C9QI01147Aen
dc.identifier.issn2052-1553
dc.identifier.otherORCID: /0000-0002-9527-6418/work/64697455
dc.identifier.otherORCID: /0000-0002-5366-9168/work/64697469
dc.identifier.otherORCID: /0000-0001-7183-6022/work/64697942
dc.identifier.urihttps://hdl.handle.net/10023/20867
dc.descriptionEZ-C acknowledges the University of St Andrews and EPSRC (EP/M02105X/1) for financial support. We thank the EPSRC UK National Mass Spectrometry Facility at Swansea University for analytical services. We thank Umicore AG for the gift of materials.en
dc.description.abstract[2.2]Paracyclophane (pCp) scaffolds, unlike many -conjugated building blocks, have been rarely explored in supramolecular self-assembly. Herein we report the synthesis and characterization of two ligands, pCpd3py and pCpd4py , composed of a pCp core functionalized at its 7- and 15-positions respectively with 3-pyridyl and 4-pyridyl units. The self-assembly of pCpd4py with Pd2+ metal ions afforded a [Pd3( pCpd4py )6]6+ cage structure, pCpd4py-Pd , where the six pCpd4py ligands doubly bridge each edge of the Pd3 triangular core. The ligand pCpd4py and the palladium cage pCpd4py-Pd have been characterized by NMR spectroscopy, ESI-MS spectrometry and X-ray diffraction analyses and their photophysical properties investigated by steady-state and time-resolved emission spectroscopy as well as Time-Dependent Density Functional Theory calculations.
dc.format.extent1038089
dc.language.isoeng
dc.relation.ispartofInorganic Chemistry Frontiersen
dc.subjectLuminescent palladium cageen
dc.subject[2.2]paracyclophane ligandsen
dc.subjectSupramolecular assemblyen
dc.subjectQD Chemistryen
dc.subjectDASen
dc.subject.lccQDen
dc.titleA Pd3L6 supramolecular cage incorporating photoactive [2.2]paracyclophane Unitsen
dc.typeJournal articleen
dc.contributor.sponsorEPSRCen
dc.contributor.institutionUniversity of St Andrews. Organic Semiconductor Centreen
dc.contributor.institutionUniversity of St Andrews. School of Chemistryen
dc.contributor.institutionUniversity of St Andrews. EaSTCHEMen
dc.identifier.doi10.1039/C9QI01147A
dc.description.statusPeer revieweden
dc.date.embargoedUntil2020-11-01
dc.identifier.grantnumberEP/M02105X/1en


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