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dc.contributor.authorRota Martir, Diego
dc.contributor.authorDelforce, Lucie
dc.contributor.authorCordes, David B.
dc.contributor.authorSlawin, Alexandra M. Z.
dc.contributor.authorWarriner, Stuart
dc.contributor.authorJacquemin, Denis
dc.contributor.authorZysman-Colman, Eli
dc.identifier.citationRota Martir , D , Delforce , L , Cordes , D B , Slawin , A M Z , Warriner , S , Jacquemin , D & Zysman-Colman , E 2019 , ' A Pd 3 L 6 supramolecular cage incorporating photoactive [2.2]paracyclophane Units ' , Inorganic Chemistry Frontiers , vol. Advance Article .
dc.identifier.otherPURE: 262929568
dc.identifier.otherPURE UUID: a6ef272c-9260-42e8-b710-66b1ea8c824b
dc.identifier.otherORCID: /0000-0002-9527-6418/work/64697455
dc.identifier.otherORCID: /0000-0002-5366-9168/work/64697469
dc.identifier.otherORCID: /0000-0001-7183-6022/work/64697942
dc.identifier.otherScopus: 85077036371
dc.identifier.otherWOS: 000503509100021
dc.descriptionEZ-C acknowledges the University of St Andrews and EPSRC (EP/M02105X/1) for financial support. We thank the EPSRC UK National Mass Spectrometry Facility at Swansea University for analytical services. We thank Umicore AG for the gift of materials.en
dc.description.abstract[2.2]Paracyclophane (pCp) scaffolds, unlike many -conjugated building blocks, have been rarely explored in supramolecular self-assembly. Herein we report the synthesis and characterization of two ligands, pCpd3py and pCpd4py , composed of a pCp core functionalized at its 7- and 15-positions respectively with 3-pyridyl and 4-pyridyl units. The self-assembly of pCpd4py with Pd2+ metal ions afforded a [Pd3( pCpd4py )6]6+ cage structure, pCpd4py-Pd , where the six pCpd4py ligands doubly bridge each edge of the Pd3 triangular core. The ligand pCpd4py and the palladium cage pCpd4py-Pd have been characterized by NMR spectroscopy, ESI-MS spectrometry and X-ray diffraction analyses and their photophysical properties investigated by steady-state and time-resolved emission spectroscopy as well as Time-Dependent Density Functional Theory calculations.
dc.relation.ispartofInorganic Chemistry Frontiersen
dc.rightsCopyright © 2019 The Author(s). This work has been made available online in accordance with publisher policies or with permission. Permission for further reuse of this content should be sought from the publisher or the rights holder. This is the author created accepted manuscript following peer review and may differ slightly from the final published version. The final published version of this work is available at
dc.subjectLuminescent palladium cageen
dc.subject[2.2]paracyclophane ligandsen
dc.subjectSupramolecular assemblyen
dc.subjectQD Chemistryen
dc.titleA Pd3L6 supramolecular cage incorporating photoactive [2.2]paracyclophane Unitsen
dc.typeJournal articleen
dc.contributor.institutionUniversity of St Andrews. Organic Semiconductor Centreen
dc.contributor.institutionUniversity of St Andrews. School of Chemistryen
dc.contributor.institutionUniversity of St Andrews. EaSTCHEMen
dc.description.statusPeer revieweden

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