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A Pd3L6 supramolecular cage incorporating photoactive [2.2]paracyclophane Units
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dc.contributor.author | Rota Martir, Diego | |
dc.contributor.author | Delforce, Lucie | |
dc.contributor.author | Cordes, David B. | |
dc.contributor.author | Slawin, Alexandra M. Z. | |
dc.contributor.author | Warriner, Stuart | |
dc.contributor.author | Jacquemin, Denis | |
dc.contributor.author | Zysman-Colman, Eli | |
dc.date.accessioned | 2020-11-01T00:38:28Z | |
dc.date.available | 2020-11-01T00:38:28Z | |
dc.date.issued | 2019-11-01 | |
dc.identifier | 262929568 | |
dc.identifier | a6ef272c-9260-42e8-b710-66b1ea8c824b | |
dc.identifier | 85077036371 | |
dc.identifier | 000503509100021 | |
dc.identifier.citation | Rota Martir , D , Delforce , L , Cordes , D B , Slawin , A M Z , Warriner , S , Jacquemin , D & Zysman-Colman , E 2019 , ' A Pd 3 L 6 supramolecular cage incorporating photoactive [2.2]paracyclophane Units ' , Inorganic Chemistry Frontiers , vol. Advance Article . https://doi.org/10.1039/C9QI01147A | en |
dc.identifier.issn | 2052-1553 | |
dc.identifier.other | ORCID: /0000-0002-9527-6418/work/64697455 | |
dc.identifier.other | ORCID: /0000-0002-5366-9168/work/64697469 | |
dc.identifier.other | ORCID: /0000-0001-7183-6022/work/64697942 | |
dc.identifier.uri | https://hdl.handle.net/10023/20867 | |
dc.description | EZ-C acknowledges the University of St Andrews and EPSRC (EP/M02105X/1) for financial support. We thank the EPSRC UK National Mass Spectrometry Facility at Swansea University for analytical services. We thank Umicore AG for the gift of materials. | en |
dc.description.abstract | [2.2]Paracyclophane (pCp) scaffolds, unlike many -conjugated building blocks, have been rarely explored in supramolecular self-assembly. Herein we report the synthesis and characterization of two ligands, pCpd3py and pCpd4py , composed of a pCp core functionalized at its 7- and 15-positions respectively with 3-pyridyl and 4-pyridyl units. The self-assembly of pCpd4py with Pd2+ metal ions afforded a [Pd3( pCpd4py )6]6+ cage structure, pCpd4py-Pd , where the six pCpd4py ligands doubly bridge each edge of the Pd3 triangular core. The ligand pCpd4py and the palladium cage pCpd4py-Pd have been characterized by NMR spectroscopy, ESI-MS spectrometry and X-ray diffraction analyses and their photophysical properties investigated by steady-state and time-resolved emission spectroscopy as well as Time-Dependent Density Functional Theory calculations. | |
dc.format.extent | 1038089 | |
dc.language.iso | eng | |
dc.relation.ispartof | Inorganic Chemistry Frontiers | en |
dc.subject | Luminescent palladium cage | en |
dc.subject | [2.2]paracyclophane ligands | en |
dc.subject | Supramolecular assembly | en |
dc.subject | QD Chemistry | en |
dc.subject | DAS | en |
dc.subject.lcc | QD | en |
dc.title | A Pd3L6 supramolecular cage incorporating photoactive [2.2]paracyclophane Units | en |
dc.type | Journal article | en |
dc.contributor.sponsor | EPSRC | en |
dc.contributor.institution | University of St Andrews. Organic Semiconductor Centre | en |
dc.contributor.institution | University of St Andrews. School of Chemistry | en |
dc.contributor.institution | University of St Andrews. EaSTCHEM | en |
dc.identifier.doi | 10.1039/C9QI01147A | |
dc.description.status | Peer reviewed | en |
dc.date.embargoedUntil | 2020-11-01 | |
dc.identifier.grantnumber | EP/M02105X/1 | en |
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