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A consecutive process for C–C and C–N bond formation with high enantio-and diastereocontrol : direct reductive amination of chiral ketones using hydrogenation catalysts
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dc.contributor.author | Gilbert, Sophie H. | |
dc.contributor.author | Viseur, Virginie | |
dc.contributor.author | Clarke, Matthew L. | |
dc.date.accessioned | 2020-05-10T05:07:20Z | |
dc.date.available | 2020-05-10T05:07:20Z | |
dc.date.issued | 2019-06-07 | |
dc.identifier | 259049136 | |
dc.identifier | 7014ad21-2fc6-485b-be12-f55512fdd12f | |
dc.identifier | 85066436488 | |
dc.identifier | 000471038300012 | |
dc.identifier.citation | Gilbert , S H , Viseur , V & Clarke , M L 2019 , ' A consecutive process for C–C and C–N bond formation with high enantio-and diastereocontrol : direct reductive amination of chiral ketones using hydrogenation catalysts ' , Chemical Communications , vol. 55 , no. 45 , pp. 6409-6412 . https://doi.org/10.1039/c9cc00923j | en |
dc.identifier.issn | 1359-7345 | |
dc.identifier.other | ORCID: /0000-0002-2444-1244/work/59464624 | |
dc.identifier.uri | https://hdl.handle.net/10023/19907 | |
dc.description | Authors thank the University of St Andrews, and the EPSRC Centre for Doctoral Training in Critical Resource Catalysis (CRITICAT) for financial support [PhD studentship to SG; Grant code: EP/L016419/1]. | en |
dc.description.abstract | High diastereoselectivity was observed in the Rh-catalysed reductive amination of 3-arylcyclohexanones to form tertiary amines. This was incorporated into a one-pot enantioselective conjugate addition and diastereoselective reductive amination, including an example of assisted tandem catalysis. | |
dc.format.extent | 4 | |
dc.format.extent | 516550 | |
dc.language.iso | eng | |
dc.relation.ispartof | Chemical Communications | en |
dc.subject | Asymmetric hydrogenation | en |
dc.subject | Reductive amination | en |
dc.subject | Homogeneous catalysis | en |
dc.subject | QD Chemistry | en |
dc.subject | DAS | en |
dc.subject.lcc | QD | en |
dc.title | A consecutive process for C–C and C–N bond formation with high enantio-and diastereocontrol : direct reductive amination of chiral ketones using hydrogenation catalysts | en |
dc.type | Journal article | en |
dc.contributor.sponsor | EPSRC | en |
dc.contributor.institution | University of St Andrews. School of Chemistry | en |
dc.contributor.institution | University of St Andrews. EaSTCHEM | en |
dc.identifier.doi | https://doi.org/10.1039/c9cc00923j | |
dc.description.status | Peer reviewed | en |
dc.date.embargoedUntil | 2020-05-10 | |
dc.identifier.grantnumber | EP/L016419/1 | en |
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