Correlating Pt-P bond lengths and Pt-P coupling constants

Waddell, Paul G.; Slawin, Alexandra M. Z.; Woollins, J. Derek

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dc.contributor.author	Waddell, Paul G.
dc.contributor.author	Slawin, Alexandra M. Z.
dc.contributor.author	Woollins, J. Derek
dc.date.accessioned	2011-08-15T23:20:31Z
dc.date.available	2011-08-15T23:20:31Z
dc.date.issued	2010-08-16
dc.identifier.citation	Waddell , P G , Slawin , A M Z & Woollins , J D 2010 , ' Correlating Pt-P bond lengths and Pt-P coupling constants ' , Dalton Transactions , vol. 39 , no. 37 , pp. 8620-8625 . https://doi.org/10.1039/c003256e	en
dc.identifier.issn	1477-9226
dc.identifier.other	PURE: 4638654
dc.identifier.other	PURE UUID: ab604328-1d42-4122-b770-30cd2860f5b1
dc.identifier.other	WOS: 000281736500007
dc.identifier.other	Scopus: 77956473473
dc.identifier.other	ORCID: /0000-0002-9527-6418/work/56862002
dc.identifier.other	ORCID: /0000-0002-1498-9652/work/31779247
dc.identifier.uri	https://hdl.handle.net/10023/1980
dc.description.abstract	The X-ray structures of (5) cis-PtBr2(P(OMe)(3))(2), (6) cis-PtBr2(P(OMe)(2)Ph)(2), (7) cis-PtBr2(P(OMe)Ph-2)(2), (8) cis-PtBr2(PPh3)(2), (9) cis-PtI2(P(OMe)(3))(2), (10) cis-PtI2(P(OMe)(2)Ph)(2), (11) cis-PtI2(P(OMe)Ph-2)(2) and (12) cis-PtI2(PPh3)(2) are reported and compared with the previously reported chloride analogues. The magnitude of the J{Pt-P} varies linearly with the Pt-P bond length (l(Pt-P) = 2.421 - J/24255) for these 12 complexes.
dc.format.extent	6
dc.language.iso	eng
dc.relation.ispartof	Dalton Transactions	en
dc.rights	This is the author's accepted version of this article. The published version (c)Royal Society of Chemistry is available from DOI: 10.1039/C003256E	en
dc.subject	Nuclear-magnetic-resonance	en
dc.subject	X-ray-structure	en
dc.subject	Tertiary phosphine complexes	en
dc.subject	Transition-metal-complexes	en
dc.subject	Solid-state structures	en
dc.subject	Platinum(ii) complexes	en
dc.subject	Crystal-structures	en
dc.subject	Molecular-structure	en
dc.subject	Phosphorus ligands	en
dc.subject	Stacking compounds	en
dc.subject	QD Chemistry	en
dc.subject.lcc	QD	en
dc.title	Correlating Pt-P bond lengths and Pt-P coupling constants	en
dc.type	Journal article	en
dc.description.version	Postprint	en
dc.contributor.institution	University of St Andrews. School of Chemistry	en
dc.contributor.institution	University of St Andrews. EaSTCHEM	en
dc.identifier.doi	https://doi.org/10.1039/c003256e
dc.description.status	Peer reviewed	en
dc.date.embargoedUntil	2011-08-16

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