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Title: Correlating Pt-P bond lengths and Pt-P coupling constants
Authors: Waddell, Paul G.
Slawin, Alexandra M. Z.
Woollins, J. Derek
Keywords: Nuclear-magnetic-resonance
Tertiary phosphine complexes
Solid-state structures
Platinum(ii) complexes
Phosphorus ligands
Stacking compounds
QD Chemistry
Issue Date: 16-Aug-2010
Citation: Waddell , P G , Slawin , A M Z & Woollins , J D 2010 , ' Correlating Pt-P bond lengths and Pt-P coupling constants ' Dalton Transactions , vol 39 , no. 37 , pp. 8620-8625 . , 10.1039/c003256e
Abstract: The X-ray structures of (5) cis-PtBr2(P(OMe)(3))(2), (6) cis-PtBr2(P(OMe)(2)Ph)(2), (7) cis-PtBr2(P(OMe)Ph-2)(2), (8) cis-PtBr2(PPh3)(2), (9) cis-PtI2(P(OMe)(3))(2), (10) cis-PtI2(P(OMe)(2)Ph)(2), (11) cis-PtI2(P(OMe)Ph-2)(2) and (12) cis-PtI2(PPh3)(2) are reported and compared with the previously reported chloride analogues. The magnitude of the J{Pt-P} varies linearly with the Pt-P bond length (l(Pt-P) = 2.421 - J/24255) for these 12 complexes.
Version: Postprint
Status: Peer reviewed
ISSN: 1477-9226
Type: Journal article
Rights: This is the author's accepted version of this article. The published version (c)Royal Society of Chemistry is available from DOI: 10.1039/C003256E
Appears in Collections:University of St Andrews Research
Chemistry Research

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