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Aerobic synthesis of N-sulfonylamidines mediated by N-heterocyclic carbene copper(I) catalysts

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dc.contributor.authorLazreg, Faïma
dc.contributor.authorVasseur, Marie
dc.contributor.authorSlawin, Alexandra M.Z.
dc.contributor.authorCazin, Catherine S.J.
dc.date.accessioned2020-04-07T11:30:02Z
dc.date.available2020-04-07T11:30:02Z
dc.date.issued2020-03-24
dc.identifier267189101
dc.identifierc1caad1d-3594-4883-9c02-3b4c3defb919
dc.identifier85082141655
dc.identifier000521194100001
dc.identifier.citationLazreg , F , Vasseur , M , Slawin , A M Z & Cazin , C S J 2020 , ' Aerobic synthesis of N -sulfonylamidines mediated by N-heterocyclic carbene copper(I) catalysts ' , Beilstein Journal of Organic Chemistry , vol. 16 , pp. 482-491 . https://doi.org/10.3762/bjoc.16.43en
dc.identifier.issn1860-5397
dc.identifier.otherORCID: /0000-0002-9527-6418/work/71559613
dc.identifier.urihttps://hdl.handle.net/10023/19762
dc.descriptionThe authors gratefully acknowledge the EPSRC National Mass Spectroscopy Facilities for the HMRS analysis at the University of Swansea.en
dc.description.abstractA new catalytic strategy for the one-pot synthesis of N-sulfonylamidines is described. The cationic copper(I) complexes were found to be highly active and efficient under mild conditions in air and in the absence of solvent. A copper acetylide is proposed as key intermediate in this transformation.
dc.format.extent10
dc.format.extent930680
dc.language.isoeng
dc.relation.ispartofBeilstein Journal of Organic Chemistryen
dc.subjectCatalysisen
dc.subjectCopperen
dc.subjectCopper catalysisen
dc.subjectN-heterocyclic carbeneen
dc.subjectSolvent-freeen
dc.subjectSulfonylamidinesen
dc.subjectQD Chemistryen
dc.subjectOrganic Chemistryen
dc.subjectDASen
dc.subject.lccQDen
dc.titleAerobic synthesis of N-sulfonylamidines mediated by N-heterocyclic carbene copper(I) catalystsen
dc.typeJournal articleen
dc.contributor.institutionUniversity of St Andrews. School of Chemistryen
dc.contributor.institutionUniversity of St Andrews. EaSTCHEMen
dc.identifier.doi10.3762/bjoc.16.43
dc.description.statusPeer revieweden
dc.identifier.urlhttps://www.beilstein-journals.org/bjoc/content/supplementary/1860-5397-16-43-S1.pdfen
dc.identifier.urlhttps://www.beilstein-journals.org/bjoc/content/supplementary/1860-5397-16-43-S2.cifen
dc.identifier.urlhttps://www.beilstein-journals.org/bjoc/content/supplementary/1860-5397-16-43-S3.cifen
dc.identifier.urlhttps://www.beilstein-journals.org/bjoc/content/supplementary/1860-5397-16-43-S4.cifen


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