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dc.contributor.authorCarboni, M.
dc.contributor.authorManzi, J.
dc.contributor.authorArmstrong, A. R.
dc.contributor.authorBillaud, J.
dc.contributor.authorBrutti, Sergio
dc.contributor.authorYounesi, R.
dc.date.accessioned2020-02-07T00:35:15Z
dc.date.available2020-02-07T00:35:15Z
dc.date.issued2019-02-07
dc.identifier.citationCarboni , M , Manzi , J , Armstrong , A R , Billaud , J , Brutti , S & Younesi , R 2019 , ' Analysis of the solid electrolyte interphase on hard carbon electrodes in sodium-ion batteries ' , ChemElectroChem , vol. Early View . https://doi.org/10.1002/celc.201801621en
dc.identifier.issn2196-0216
dc.identifier.otherPURE: 257339461
dc.identifier.otherPURE UUID: 9a123fe7-32c8-4f3f-ab44-f100b8c0aa46
dc.identifier.otherRIS: urn:F769A116EC36DC879B5940C45FAEDDE7
dc.identifier.otherScopus: 85061323622
dc.identifier.otherORCID: /0000-0003-1937-0936/work/54181485
dc.identifier.otherWOS: 000463752300017
dc.identifier.urihttp://hdl.handle.net/10023/19423
dc.descriptionSB would like to thank the Italian Government for the funding through the FFARB scheme and Basilicata Innovazione project for the financial support through the specific program “Validazione dei risultati della Ricerca - Progetto di Convalida 2014-2015 - Prestazioni e analisi di fallimento di un dispositivo sodio-ione completo per accumulo reversibile di energia”. RY is grateful to the Swedish Research Council for Environment, Agricultural Sciences and Spatial Planning (FORMAS) (project number 2016-01257) and STandUp for Energy for financial support.en
dc.description.abstractThe composition, morphology and evolution of the solid electrolyte interphase (SEI) formed on hard carbon (HC) electrodes upon cycling in sodium-ion batteries are here investigated. A microporous HC was prepared by pyrolysis of D-(+)-Glucose at 1000°C followed by ball-milling. HC electrodes were galvanostatically cycled at room temperature in sodium-ion half-cells using an aprotic electrolyte of 1 M sodium bis(trifluoromethanesulfonyl)imide dissolved in propylene carbonate with 3 wt% fluoroethylene carbonate additive. The evolution of the electrode/electrolyte interface was studied by impedance spectroscopy upon cycling and ex situ by spectroscopy and microscopy. The irreversible capacity displayed by the HC electrodes in the first galvanostatic cycle is probably due to the accumulation of redox inactive NaxC phases and the precipitation of a porous, organic-inorganic hybrid SEI layer over the HC electrodes. This passivation film further evolves in morphology and composition upon cycling and stabilizes after approximately 10 galvanostatic cycles at low current rates.
dc.language.isoeng
dc.relation.ispartofChemElectroChemen
dc.rightsCopyright © 2019 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim. This work has been made available online in accordance with the publisher’s policies. This is the author created, accepted version manuscript following peer review and may differ slightly from the final published version. The final published version of this work is available at https://doi.org/10.1002/celc.201801621en
dc.subjectSodium batteryen
dc.subjectHard carbonen
dc.subjectSolid electrolyte interphaseen
dc.subjectSEIen
dc.subjectFluoroethylene carbonateen
dc.subjectQD Chemistryen
dc.subjectNDASen
dc.subject.lccQDen
dc.titleAnalysis of the solid electrolyte interphase on hard carbon electrodes in sodium-ion batteriesen
dc.typeJournal articleen
dc.description.versionPostprinten
dc.contributor.institutionUniversity of St Andrews.School of Chemistryen
dc.identifier.doihttps://doi.org/10.1002/celc.201801621
dc.description.statusPeer revieweden
dc.date.embargoedUntil2020-02-07


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