A bifunctional MOF catalyst containing metal-phosphine and Lewis acidic active sites

Prasad, Ram R. R.; Dawson, Daniel M.; Cox, Paul A.; Ashbrook, Sharon E.; Wright, Paul A.; Clarke, Matthew L.

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dc.contributor.author	Prasad, Ram R. R.
dc.contributor.author	Dawson, Daniel M.
dc.contributor.author	Cox, Paul A.
dc.contributor.author	Ashbrook, Sharon E.
dc.contributor.author	Wright, Paul A.
dc.contributor.author	Clarke, Matthew L.
dc.date.accessioned	2019-09-18T23:37:20Z
dc.date.available	2019-09-18T23:37:20Z
dc.date.issued	2018-10-12
dc.identifier.citation	Prasad , R R R , Dawson , D M , Cox , P A , Ashbrook , S E , Wright , P A & Clarke , M L 2018 , ' A bifunctional MOF catalyst containing metal-phosphine and Lewis acidic active sites ' , Chemistry - A European Journal , vol. 24 , no. 57 , pp. 15309-15318 . https://doi.org/10.1002/chem.201803094	en
dc.identifier.issn	0947-6539
dc.identifier.other	PURE: 253867645
dc.identifier.other	PURE UUID: 89da9aca-aefe-44b0-950d-9be20d475bb5
dc.identifier.other	Scopus: 85053690552
dc.identifier.other	ORCID: /0000-0002-8724-6358/work/49052220
dc.identifier.other	ORCID: /0000-0002-4538-6782/work/56638959
dc.identifier.other	ORCID: /0000-0002-2444-1244/work/59464618
dc.identifier.other	ORCID: /0000-0002-8110-4535/work/59464836
dc.identifier.other	WOS: 000447124800025
dc.identifier.other	ORCID: /0000-0002-4243-9957/work/62668286
dc.identifier.uri	https://hdl.handle.net/10023/18504
dc.description	Funding: UK Engineering and Physical Sciences Research Council (EPSRC) and CRITICAT Centre for Doctoral Training for financial support [Ph.D studentship to R. R. R. P; Grant code: EP/L016419/1].	en
dc.description.abstract	Post‐synthetic modification of the hafnium metal–organic framework MOF‐808(Hf) to include triarylphosphine ligands is reported. Sulfonated phenylphosphines are incorporated without oxidation to give a “MOF ligand” that can complex late transition metals such as Ir and Rh to give a bifunctional catalyst containing both metal–phosphine complexes and the Lewis acidic framework hafnium metal sites. The metallated phosphine‐bearing MOFs act as fully heterogeneous bifunctional catalysts for tandem reductive amination and hydroaminomethylation reactions.
dc.language.iso	eng
dc.relation.ispartof	Chemistry - A European Journal	en
dc.rights	© 2018 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim. This work has been made available online in accordance with the publisher’s policies. This is the author created accepted version manuscript following peer review and as such may differ slightly from the final published version. The final published version of this work is available at https://doi.org/10.1002/chem.201803094	en
dc.subject	Metal-organic frameworks	en
dc.subject	MOF-808(Hf)	en
dc.subject	PSM	en
dc.subject	Phosphines	en
dc.subject	Reductive amination	en
dc.subject	QD Chemistry	en
dc.subject	DAS	en
dc.subject	BDC	en
dc.subject	R2C	en
dc.subject.lcc	QD	en
dc.title	A bifunctional MOF catalyst containing metal-phosphine and Lewis acidic active sites	en
dc.type	Journal article	en
dc.contributor.sponsor	EPSRC	en
dc.contributor.sponsor	The Royal Society	en
dc.description.version	Postprint	en
dc.contributor.institution	University of St Andrews. School of Chemistry	en
dc.contributor.institution	University of St Andrews. EaSTCHEM	en
dc.identifier.doi	https://doi.org/10.1002/chem.201803094
dc.description.status	Peer reviewed	en
dc.date.embargoedUntil	2019-09-19
dc.identifier.grantnumber	EP/L016419/1	en
dc.identifier.grantnumber	WM150021	en

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