A bifunctional MOF catalyst containing metal-phosphine and Lewis acidic active sites
Abstract
Post‐synthetic modification of the hafnium metal–organic framework MOF‐808(Hf) to include triarylphosphine ligands is reported. Sulfonated phenylphosphines are incorporated without oxidation to give a “MOF ligand” that can complex late transition metals such as Ir and Rh to give a bifunctional catalyst containing both metal–phosphine complexes and the Lewis acidic framework hafnium metal sites. The metallated phosphine‐bearing MOFs act as fully heterogeneous bifunctional catalysts for tandem reductive amination and hydroaminomethylation reactions.
Citation
Prasad , R R R , Dawson , D M , Cox , P A , Ashbrook , S E , Wright , P A & Clarke , M L 2018 , ' A bifunctional MOF catalyst containing metal-phosphine and Lewis acidic active sites ' , Chemistry - A European Journal , vol. 24 , no. 57 , pp. 15309-15318 . https://doi.org/10.1002/chem.201803094
Publication
Chemistry - A European Journal
Status
Peer reviewed
ISSN
0947-6539Type
Journal article
Rights
© 2018 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim. This work has been made available online in accordance with the publisher’s policies. This is the author created accepted version manuscript following peer review and as such may differ slightly from the final published version. The final published version of this work is available at https://doi.org/10.1002/chem.201803094
Description
Funding: UK Engineering and Physical Sciences Research Council (EPSRC) and CRITICAT Centre for Doctoral Training for financial support [Ph.D studentship to R. R. R. P; Grant code: EP/L016419/1].Collections
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