A bifunctional MOF catalyst containing metal-phosphine and Lewis acidic active sites
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Post‐synthetic modification of the hafnium metal–organic framework MOF‐808(Hf) to include triarylphosphine ligands is reported. Sulfonated phenylphosphines are incorporated without oxidation to give a “MOF ligand” that can complex late transition metals such as Ir and Rh to give a bifunctional catalyst containing both metal–phosphine complexes and the Lewis acidic framework hafnium metal sites. The metallated phosphine‐bearing MOFs act as fully heterogeneous bifunctional catalysts for tandem reductive amination and hydroaminomethylation reactions.
Prasad , R R R , Dawson , D M , Cox , P A , Ashbrook , S E , Wright , P A & Clarke , M L 2018 , ' A bifunctional MOF catalyst containing metal-phosphine and Lewis acidic active sites ' , Chemistry - A European Journal , vol. 24 , no. 57 , pp. 15309-15318 . https://doi.org/10.1002/chem.201803094
Chemistry - A European Journal
© 2018 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim. This work has been made available online in accordance with the publisher’s policies. This is the author created accepted version manuscript following peer review and as such may differ slightly from the final published version. The final published version of this work is available at https://doi.org/10.1002/chem.201803094