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dc.contributor.authorHua, Guoxiong
dc.contributor.authorFuller, Amy L.
dc.contributor.authorLi, Yang
dc.contributor.authorSlawin, Alexandra M. Z.
dc.contributor.authorWoollins, J. Derek
dc.date.accessioned2011-04-01T14:01:03Z
dc.date.available2011-04-01T14:01:03Z
dc.date.issued2010-08
dc.identifier4638533
dc.identifier03ae9bbe-294c-4f80-affa-8ad141e5cb4e
dc.identifier000280514300013
dc.identifier77955075518
dc.identifier.citationHua , G , Fuller , A L , Li , Y , Slawin , A M Z & Woollins , J D 2010 , ' Synthesis and X-ray structures of new phosphorus-selenium heterocycles with an E-P(Se)-E ' (E, E ' = N, S, Se) linkage ' , New Journal of Chemistry , vol. 34 , no. 8 , pp. 1565-1571 . https://doi.org/10.1039/b9nj00570fen
dc.identifier.issn1144-0546
dc.identifier.otherORCID: /0000-0002-9527-6418/work/56861399
dc.identifier.otherORCID: /0000-0002-1498-9652/work/31779248
dc.identifier.urihttps://hdl.handle.net/10023/1766
dc.descriptionThis work is funded by the EPSRC UKen
dc.description.abstractRefluxing a toluene solution of Woollins' reagent, WR, with difunctional aromatic substrates (aryldiamines and aryldithiols) leads to a series of novel five-to seven-membered heterocycles 2a-e, 4a, 4b and 6a-c with an E-P(Se)-E' (E, E' = N, S, Se) linkage in 7-98% isolated yields. This method offers a new approach to the library of phosphorus-selenium heterocyclic compounds. All new compounds have been characterized by IR, H-1, C-13, P-31, Se-77 NMR, mass spectrometry and elemental analysis or accurate mass measurement. Four representative X-ray structures are reported.
dc.format.extent7
dc.format.extent461420
dc.language.isoeng
dc.relation.ispartofNew Journal of Chemistryen
dc.subjectCrystal-structuresen
dc.subjectChemistryen
dc.subject(PHP(SE)(MU-SE))(2)en
dc.subjectCrystallographyen
dc.subjectCynamidesen
dc.subjectReactivityen
dc.subjectRingsen
dc.subjectQD Chemistryen
dc.subject.lccQDen
dc.titleSynthesis and X-ray structures of new phosphorus-selenium heterocycles with an E-P(Se)-E ' (E, E ' = N, S, Se) linkageen
dc.typeJournal articleen
dc.contributor.institutionUniversity of St Andrews. School of Chemistryen
dc.contributor.institutionUniversity of St Andrews. EaSTCHEMen
dc.identifier.doi10.1039/b9nj00570f
dc.description.statusPeer revieweden


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