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Manganese catalyzed hydrogenation of enantiomerically pure esters
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| dc.contributor.author | Widegren, Magnus B. | |
| dc.contributor.author | Clarke, Matthew L. | |
| dc.date.accessioned | 2019-04-18T23:38:08Z | |
| dc.date.available | 2019-04-18T23:38:08Z | |
| dc.date.issued | 2018-05-04 | |
| dc.identifier | 252805467 | |
| dc.identifier | 2477b1bf-1f16-4f5f-938c-4adc5e57c9e9 | |
| dc.identifier | 85046677522 | |
| dc.identifier | 000431726900036 | |
| dc.identifier.citation | Widegren , M B & Clarke , M L 2018 , ' Manganese catalyzed hydrogenation of enantiomerically pure esters ' , Organic Letters , vol. 20 , no. 9 , pp. 2654-2658 . https://doi.org/10.1021/acs.orglett.8b00864 | en |
| dc.identifier.issn | 1523-7060 | |
| dc.identifier.other | ORCID: /0000-0002-2444-1244/work/62668378 | |
| dc.identifier.uri | https://hdl.handle.net/10023/17545 | |
| dc.description | The authors thank the EPSRC for DTG funding for MBW. The technical support staff at St Andrews are also gratefully acknowledged. The research data supporting this publication can be accessed at: dx.doi.org/10.17630/29308cf7-b6b6- 4b1b-809b-a12fe91b250f | en |
| dc.description.abstract | A manganese-catalyzed hydrogenation of esters has been accomplished with TON up to 1000, using cheap, environmentally benign, potassium carbonate and simple alcohols as activator and solvent, respectively. The weakly basic conditions lead to good functional group tolerance and enable the hydrogenation of enantiomerically enriched α-chiral esters with essentially no loss of stereochemical integrity. | |
| dc.format.extent | 5 | |
| dc.format.extent | 510270 | |
| dc.language.iso | eng | |
| dc.relation.ispartof | Organic Letters | en |
| dc.subject | QD Chemistry | en |
| dc.subject | DAS | en |
| dc.subject.lcc | QD | en |
| dc.title | Manganese catalyzed hydrogenation of enantiomerically pure esters | en |
| dc.type | Journal article | en |
| dc.contributor.institution | University of St Andrews. School of Chemistry | en |
| dc.contributor.institution | University of St Andrews. EaSTCHEM | en |
| dc.identifier.doi | 10.1021/acs.orglett.8b00864 | |
| dc.description.status | Peer reviewed | en |
| dc.date.embargoedUntil | 2019-04-19 |
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