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A new route to α,ω-diamines from hydrogenation of dicarboxylic acids and their derivatives in the presence of amines
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dc.contributor.author | Shi, Yiping | |
dc.contributor.author | Kamer, Paulus Clemens Jozef | |
dc.contributor.author | Cole-Hamilton, David John | |
dc.date.accessioned | 2018-10-10T23:48:44Z | |
dc.date.available | 2018-10-10T23:48:44Z | |
dc.date.issued | 2017-10-11 | |
dc.identifier | 251540503 | |
dc.identifier | 89e6d829-5c62-410d-8ef9-3d88934c22be | |
dc.identifier | 85034236508 | |
dc.identifier | 000415115600020 | |
dc.identifier.citation | Shi , Y , Kamer , P C J & Cole-Hamilton , D J 2017 , ' A new route to α,ω-diamines from hydrogenation of dicarboxylic acids and their derivatives in the presence of amines ' , Green Chemistry , vol. 19 , pp. 5460-5466 . https://doi.org/10.1039/C7GC02838E | en |
dc.identifier.issn | 1463-9262 | |
dc.identifier.uri | https://hdl.handle.net/10023/16186 | |
dc.description | We thank the EPSRC for the critical mass grant 'Clean Catalysis for Sustainable Development' (EP/J018139/1), Sasol Technology, UK for a case studentship (Y. S.) and the EPSRC UK National Mass Spectrometry Facility at Swansea University for mass spectrometric analysis | en |
dc.description.abstract | A new and selective route for the synthesis of polymer precursors, primary diamines or N-substituted diamines, from dicarboxylic acids, diesters, diamides and diols using a Ru/ triphos catalyst is reported. Excellent conversions and yields are obtained under optimised reaction conditions. The reactions worked very well using 1,4-dioxane as solvent, but the greener solvent, 2-methyl tetrahydrofuran, also gave very similar results. This method provides a potential route to converting waste biomass to value added materials. The reaction is proposed to go through both amide and aldehyde pathways. | |
dc.format.extent | 660294 | |
dc.language.iso | eng | |
dc.relation.ispartof | Green Chemistry | en |
dc.subject | QD Chemistry | en |
dc.subject | NDAS | en |
dc.subject.lcc | QD | en |
dc.title | A new route to α,ω-diamines from hydrogenation of dicarboxylic acids and their derivatives in the presence of amines | en |
dc.type | Journal article | en |
dc.contributor.sponsor | EPSRC | en |
dc.contributor.institution | University of St Andrews. School of Chemistry | en |
dc.contributor.institution | University of St Andrews. EaSTCHEM | en |
dc.identifier.doi | 10.1039/C7GC02838E | |
dc.description.status | Peer reviewed | en |
dc.date.embargoedUntil | 2018-10-11 | |
dc.identifier.grantnumber | EP/J018139/1 | en |
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