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An expanded MIL-53-type coordination polymer with a reactive pendant ligand

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dc.contributor.authorKunicki, Hannah
dc.contributor.authorChamberlain, Thomas
dc.contributor.authorClarkson, Guy
dc.contributor.authorKashtiban, Reza
dc.contributor.authorHooper, Joseph E.
dc.contributor.authorDawson, Daniel M.
dc.contributor.authorAshbrook, Sharon E.
dc.contributor.authorWalton, Richard
dc.date.accessioned2018-07-18T14:30:05Z
dc.date.available2018-07-18T14:30:05Z
dc.date.issued2018-07-18
dc.identifier.citationKunicki , H , Chamberlain , T , Clarkson , G , Kashtiban , R , Hooper , J E , Dawson , D M , Ashbrook , S E & Walton , R 2018 , ' An expanded MIL-53-type coordination polymer with a reactive pendant ligand ' , CrystEngComm , vol. Advance Article . https://doi.org/10.1039/C8CE00891Den
dc.identifier.issn1466-8033
dc.identifier.otherPURE: 253442487
dc.identifier.otherPURE UUID: f726367e-923b-49bd-9a13-ed7f21702a73
dc.identifier.otherScopus: 85051167675
dc.identifier.otherORCID: /0000-0002-4538-6782/work/56638927
dc.identifier.otherORCID: /0000-0002-8110-4535/work/59464830
dc.identifier.otherWOS: 000441580600001
dc.identifier.urihttps://hdl.handle.net/10023/15542
dc.descriptionThe authors acknowledge the University of Warwick Undergraduate Research Support Scheme for award of a bursary to TWC. The EPSRC’s UK National Crystallography Service at the University of Southampton is thanked for one of the data sets. The UK 850 MHz solid-state NMR Facility was funded by EPSRC and BBSRC (contract reference PR140003), as well as the University of Warwick including via part funding through Birmingham Science City Advanced Materials Projects 1 and 2 supported by Advantage West Midlands (AWM) and the European Regional Development Fund (ERDF). SEA would like to thank the ERC (EU FP7 Consolidator Grant 614290 “EXONMR”).en
dc.description.abstractA coordination polymer with a structure isoreticular to MIL-53, but containing a divalent metal cation (Co2+ or Mg2+) and a coordinating 4-styrylpyridine-N-oxide ligand, crystallises under solvothermal conditions; the pendant ligand can be brominated, with evidence from powder X-ray diffraction, element mapping and 81Br solid- state NMR for this post-synthesis modification.
dc.format.extent4
dc.language.isoeng
dc.relation.ispartofCrystEngCommen
dc.rights© 2018 The Author(s). Open Access Article. This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.en
dc.subjectQD Chemistryen
dc.subjectDASen
dc.subject.lccQDen
dc.titleAn expanded MIL-53-type coordination polymer with a reactive pendant liganden
dc.typeJournal articleen
dc.contributor.sponsorEuropean Research Councilen
dc.description.versionPublisher PDFen
dc.contributor.institutionUniversity of St Andrews. School of Chemistryen
dc.contributor.institutionUniversity of St Andrews. EaSTCHEMen
dc.identifier.doihttps://doi.org/10.1039/C8CE00891D
dc.description.statusPeer revieweden
dc.identifier.grantnumber614290 - EXONMRen


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