An expanded MIL-53-type coordination polymer with a reactive pendant ligand
MetadataShow full item record
A coordination polymer with a structure isoreticular to MIL-53, but containing a divalent metal cation (Co2+ or Mg2+) and a coordinating 4-styrylpyridine-N-oxide ligand, crystallises under solvothermal conditions; the pendant ligand can be brominated, with evidence from powder X-ray diffraction, element mapping and 81Br solid- state NMR for this post-synthesis modification.
Kunicki , H , Chamberlain , T , Clarkson , G , Kashtiban , R , Hooper , J E , Dawson , D M , Ashbrook , S E & Walton , R 2018 , ' An expanded MIL-53-type coordination polymer with a reactive pendant ligand ' , CrystEngComm , vol. Advance Article . https://doi.org/10.1039/C8CE00891D
© 2018 The Author(s). Open Access Article. This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
DescriptionThe authors acknowledge the University of Warwick Undergraduate Research Support Scheme for award of a bursary to TWC. The EPSRC’s UK National Crystallography Service at the University of Southampton is thanked for one of the data sets. The UK 850 MHz solid-state NMR Facility was funded by EPSRC and BBSRC (contract reference PR140003), as well as the University of Warwick including via part funding through Birmingham Science City Advanced Materials Projects 1 and 2 supported by Advantage West Midlands (AWM) and the European Regional Development Fund (ERDF). SEA would like to thank the ERC (EU FP7 Consolidator Grant 614290 “EXONMR”).
Items in the St Andrews Research Repository are protected by copyright, with all rights reserved, unless otherwise indicated.