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An expanded MIL-53-type coordination polymer with a reactive pendant ligand

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Kunicki_2018_CrystEngComm_MIL_53_CC.pdf (1.424Mb)
Date
18/07/2018
Author
Kunicki, Hannah
Chamberlain, Thomas
Clarkson, Guy
Kashtiban, Reza
Hooper, Joseph E.
Dawson, Daniel M.
Ashbrook, Sharon E.
Walton, Richard
Funder
European Research Council
Grant ID
614290 - EXONMR
Keywords
QD Chemistry
DAS
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Abstract
A coordination polymer with a structure isoreticular to MIL-53, but containing a divalent metal cation (Co2+ or Mg2+) and a coordinating 4-styrylpyridine-N-oxide ligand, crystallises under solvothermal conditions; the pendant ligand can be brominated, with evidence from powder X-ray diffraction, element mapping and 81Br solid- state NMR for this post-synthesis modification.
Citation
Kunicki , H , Chamberlain , T , Clarkson , G , Kashtiban , R , Hooper , J E , Dawson , D M , Ashbrook , S E & Walton , R 2018 , ' An expanded MIL-53-type coordination polymer with a reactive pendant ligand ' , CrystEngComm , vol. Advance Article . https://doi.org/10.1039/C8CE00891D
Publication
CrystEngComm
Status
Peer reviewed
DOI
https://doi.org/10.1039/C8CE00891D
ISSN
1466-8033
Type
Journal article
Rights
© 2018 The Author(s). Open Access Article. This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Description
The authors acknowledge the University of Warwick Undergraduate Research Support Scheme for award of a bursary to TWC. The EPSRC’s UK National Crystallography Service at the University of Southampton is thanked for one of the data sets. The UK 850 MHz solid-state NMR Facility was funded by EPSRC and BBSRC (contract reference PR140003), as well as the University of Warwick including via part funding through Birmingham Science City Advanced Materials Projects 1 and 2 supported by Advantage West Midlands (AWM) and the European Regional Development Fund (ERDF). SEA would like to thank the ERC (EU FP7 Consolidator Grant 614290 “EXONMR”).
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  • University of St Andrews Research
URI
http://hdl.handle.net/10023/15542

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