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Aryloxide-promoted catalyst turnover in Lewis base organocatalysis

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dc.contributor.authorHartley, Will C.
dc.contributor.authorO'Riordan, Timothy J. C.
dc.contributor.authorSmith, Andrew D.
dc.date.accessioned2018-06-26T23:32:25Z
dc.date.available2018-06-26T23:32:25Z
dc.date.issued2017-08
dc.identifier249974102
dc.identifieree72c858-a734-4d86-aa6d-83c7c20bd48a
dc.identifier85021301415
dc.identifier000406065500017
dc.identifier.citationHartley , W C , O'Riordan , T J C & Smith , A D 2017 , ' Aryloxide-promoted catalyst turnover in Lewis base organocatalysis ' , Synthesis , vol. 49 , no. 15 , pp. 3303-3310 . https://doi.org/10.1055/s-0036-1589047en
dc.identifier.issn0039-7881
dc.identifier.urihttps://hdl.handle.net/10023/14646
dc.descriptionThe authors thank Syngenta and the EPSRC Centre for Doctoral Training in Critical Resource Catalysis (CRITICAT, grant code EP/L016419/1) (WCH) for funding. The European Research Council under the European Union’s Seventh Framework Programme (FP7/2007-2013) ERC Grant Agreement No. 279850 is also acknowledged (ADS). ADS thanks the Royal Society for a Wolfson Research Merit Award.en
dc.description.abstractThis short review highlights select examples of enantioselective Lewis base promoted reactions that use tertiary amine (cinchona alkaloids, isothioureas and DMAP/PPY derivatives) or NHC catalysts and employ aryloxide promoted catalyst turnover from an acyl ammonium or azolium intermediate. This review focuses on the range of strategies that have been developed within this area, and discusses their evolution and context
dc.format.extent2084103
dc.language.isoeng
dc.relation.ispartofSynthesisen
dc.subjectLewis base catalysisen
dc.subjectcatalyst turnover and releaseen
dc.subjectAryloxideen
dc.subjectIsothioureaen
dc.subjectNHCen
dc.subjectTertiary aminesen
dc.subjectQD Chemistryen
dc.subject.lccQDen
dc.titleAryloxide-promoted catalyst turnover in Lewis base organocatalysisen
dc.typeJournal itemen
dc.contributor.sponsorEuropean Commissionen
dc.contributor.sponsorEPSRCen
dc.contributor.sponsorThe Royal Societyen
dc.contributor.institutionUniversity of St Andrews. School of Chemistryen
dc.contributor.institutionUniversity of St Andrews. Biomedical Sciences Research Complexen
dc.contributor.institutionUniversity of St Andrews. EaSTCHEMen
dc.identifier.doihttps://doi.org/10.1055/s-0036-1589047
dc.description.statusPeer revieweden
dc.date.embargoedUntil2018-06-26
dc.identifier.grantnumberN/Aen
dc.identifier.grantnumberEP/L016419/1en
dc.identifier.grantnumberWM140071en


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