Aryloxide-promoted catalyst turnover in Lewis base organocatalysis
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This short review highlights select examples of enantioselective Lewis base promoted reactions that use tertiary amine (cinchona alkaloids, isothioureas and DMAP/PPY derivatives) or NHC catalysts and employ aryloxide promoted catalyst turnover from an acyl ammonium or azolium intermediate. This review focuses on the range of strategies that have been developed within this area, and discusses their evolution and context
Hartley , W C , O'Riordan , T J C & Smith , A D 2017 , ' Aryloxide-promoted catalyst turnover in Lewis base organocatalysis ' , Synthesis , vol. 49 , no. 15 , pp. 3303-3310 . https://doi.org/10.1055/s-0036-1589047
© 2017 Georg Thieme Verlag Stuttgart · New York. This work has been made available online in accordance with the publisher’s policies. This is the author created accepted version manuscript following peer review and as such may differ slightly from the final published version. The final published version of this work is available at: https://doi.org/10.1055/s-0036-1589047
DescriptionThe authors thank Syngenta and the EPSRC Centre for Doctoral Training in Critical Resource Catalysis (CRITICAT, grant code EP/L016419/1) (WCH) for funding. The European Research Council under the European Union’s Seventh Framework Programme (FP7/2007-2013) ERC Grant Agreement No. 279850 is also acknowledged (ADS). ADS thanks the Royal Society for a Wolfson Research Merit Award.
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