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Optimised synthesis and characterisation of 1-adamantyltrimethylphosphonium iodide

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dc.contributor.authorMansour, Riad
dc.contributor.authorNejman, Phillip
dc.contributor.authorTaylor, Laurence J.
dc.contributor.authorChalmers, Brian A.
dc.contributor.authorRey, Fernando
dc.contributor.authorBengueddach, Abdelkader
dc.contributor.authorWoollins, J. Derek
dc.contributor.authorSlawin, Alexandra M. Z.
dc.contributor.authorKilian, Petr
dc.date.accessioned2018-06-01T23:32:52Z
dc.date.available2018-06-01T23:32:52Z
dc.date.issued2017-09-05
dc.identifier.citationMansour , R , Nejman , P , Taylor , L J , Chalmers , B A , Rey , F , Bengueddach , A , Woollins , J D , Slawin , A M Z & Kilian , P 2017 , ' Optimised synthesis and characterisation of 1-adamantyltrimethylphosphonium iodide ' , Polyhedron , vol. 133 , pp. 302-306 . https://doi.org/10.1016/j.poly.2017.05.050en
dc.identifier.issn0277-5387
dc.identifier.otherPURE: 250088634
dc.identifier.otherPURE UUID: 8ce1b1c8-986f-476f-8dc1-7ad9ff360a94
dc.identifier.otherScopus: 85020647270
dc.identifier.otherORCID: /0000-0002-2999-2272/work/55901226
dc.identifier.otherORCID: /0000-0002-9527-6418/work/56861408
dc.identifier.otherORCID: /0000-0001-6379-3026/work/58285395
dc.identifier.otherORCID: /0000-0002-1498-9652/work/59464659
dc.identifier.otherWOS: 000405537200038
dc.identifier.urihttps://hdl.handle.net/10023/13675
dc.descriptionThis work was financially supported by the EPSRC (grant numbers EP/L505079/1 and EP/M506631/1) and COST action SM1302 SIPs. The authors thank the University of St Andrews NMR Service and the EPSRC UK National Mass Spectrometry Facility at Swansea University (NMSF).en
dc.description.abstractA synthetic route to multigram quantities of 1-adamantyltrimethylphosphonium iodide is reported. The synthesis starts from the commercially available precursor 1-adamantyl bromide and was optimised with respect to yield and ease of purification. The title compound is of interest to zeolite chemists as a potent organic structure-directing agent. Full spectroscopic characterisation data of all isolated intermediates and single crystal X-ray diffraction data of AdP(O)Cl2, [AdPMe2H]I and [AdPMe3]I (Ad = 1-adamantyl) are reported.
dc.format.extent5
dc.language.isoeng
dc.relation.ispartofPolyhedronen
dc.rights© 2017 Elsevier Ltd. All rights reserved. This work has been made available online in accordance with the publisher’s policies. This is the author created, accepted version manuscript following peer review and may differ slightly from the final published version. The final published version of this work is available at https://doi.org/10.1016/j.poly.2017.05.050en
dc.subjectOrganophosphorusen
dc.subjectPhosphoniumen
dc.subjectSynthesisen
dc.subjectAdamantyl groupen
dc.subjectOrganic Structure-directing Agenten
dc.subjectQD Chemistryen
dc.subjectDASen
dc.subject.lccQDen
dc.titleOptimised synthesis and characterisation of 1-adamantyltrimethylphosphonium iodideen
dc.typeJournal articleen
dc.description.versionPostprinten
dc.contributor.institutionUniversity of St Andrews. School of Chemistryen
dc.contributor.institutionUniversity of St Andrews. EaSTCHEMen
dc.contributor.institutionUniversity of St Andrews. Office of the Principalen
dc.identifier.doihttps://doi.org/10.1016/j.poly.2017.05.050
dc.description.statusPeer revieweden
dc.date.embargoedUntil2018-06-01


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