St Andrews Research Repository

St Andrews University Home
View Item 
  •   St Andrews Research Repository
  • University of St Andrews Research
  • University of St Andrews Research
  • University of St Andrews Research
  • View Item
  •   St Andrews Research Repository
  • University of St Andrews Research
  • University of St Andrews Research
  • University of St Andrews Research
  • View Item
  •   St Andrews Research Repository
  • University of St Andrews Research
  • University of St Andrews Research
  • University of St Andrews Research
  • View Item
  • Register / Login
JavaScript is disabled for your browser. Some features of this site may not work without it.

Optimised synthesis and characterisation of 1-adamantyltrimethylphosphonium iodide

Thumbnail
View/Open
Paper_ver44_revised.pdf (341.9Kb)
Date
05/09/2017
Author
Mansour, Riad
Nejman, Phillip
Taylor, Laurence J.
Chalmers, Brian A.
Rey, Fernando
Bengueddach, Abdelkader
Woollins, J. Derek
Slawin, Alexandra M. Z.
Kilian, Petr
Keywords
Organophosphorus
Phosphonium
Synthesis
Adamantyl group
Organic Structure-directing Agent
QD Chemistry
DAS
Metadata
Show full item record
Abstract
A synthetic route to multigram quantities of 1-adamantyltrimethylphosphonium iodide is reported. The synthesis starts from the commercially available precursor 1-adamantyl bromide and was optimised with respect to yield and ease of purification. The title compound is of interest to zeolite chemists as a potent organic structure-directing agent. Full spectroscopic characterisation data of all isolated intermediates and single crystal X-ray diffraction data of AdP(O)Cl2, [AdPMe2H]I and [AdPMe3]I (Ad = 1-adamantyl) are reported.
Citation
Mansour , R , Nejman , P , Taylor , L J , Chalmers , B A , Rey , F , Bengueddach , A , Woollins , J D , Slawin , A M Z & Kilian , P 2017 , ' Optimised synthesis and characterisation of 1-adamantyltrimethylphosphonium iodide ' , Polyhedron , vol. 133 , pp. 302-306 . https://doi.org/10.1016/j.poly.2017.05.050
Publication
Polyhedron
Status
Peer reviewed
DOI
https://doi.org/10.1016/j.poly.2017.05.050
ISSN
0277-5387
Type
Journal article
Rights
© 2017 Elsevier Ltd. All rights reserved. This work has been made available online in accordance with the publisher’s policies. This is the author created, accepted version manuscript following peer review and may differ slightly from the final published version. The final published version of this work is available at https://doi.org/10.1016/j.poly.2017.05.050
Description
This work was financially supported by the EPSRC (grant numbers EP/L505079/1 and EP/M506631/1) and COST action SM1302 SIPs. The authors thank the University of St Andrews NMR Service and the EPSRC UK National Mass Spectrometry Facility at Swansea University (NMSF).
Collections
  • University of St Andrews Research
URI
http://hdl.handle.net/10023/13675

Items in the St Andrews Research Repository are protected by copyright, with all rights reserved, unless otherwise indicated.

Advanced Search

Browse

All of RepositoryCommunities & CollectionsBy Issue DateNamesTitlesSubjectsClassificationTypeFunderThis CollectionBy Issue DateNamesTitlesSubjectsClassificationTypeFunder

My Account

Login

Open Access

To find out how you can benefit from open access to research, see our library web pages and Open Access blog. For open access help contact: openaccess@st-andrews.ac.uk.

Accessibility

Read our Accessibility statement.

How to submit research papers

The full text of research papers can be submitted to the repository via Pure, the University's research information system. For help see our guide: How to deposit in Pure.

Electronic thesis deposit

Help with deposit.

Repository help

For repository help contact: Digital-Repository@st-andrews.ac.uk.

Give Feedback

Cookie policy

This site may use cookies. Please see Terms and Conditions.

Usage statistics

COUNTER-compliant statistics on downloads from the repository are available from the IRUS-UK Service. Contact us for information.

© University of St Andrews Library

University of St Andrews is a charity registered in Scotland, No SC013532.

  • Facebook
  • Twitter