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A highly active manganese catalyst for enantioselective ketone and ester hydrogenation
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dc.contributor.author | Widegren, Magnus B. | |
dc.contributor.author | Harkness, Gavin J. | |
dc.contributor.author | Slawin, Alexandra M. Z. | |
dc.contributor.author | Cordes, David B. | |
dc.contributor.author | Clarke, Matthew L. | |
dc.date.accessioned | 2018-04-20T23:33:04Z | |
dc.date.available | 2018-04-20T23:33:04Z | |
dc.date.issued | 2017-05-15 | |
dc.identifier | 249586929 | |
dc.identifier | ca65ee1f-1438-41a7-a6d9-c4285e0a80c9 | |
dc.identifier.citation | Widegren , M B , Harkness , G J , Slawin , A M Z , Cordes , D B & Clarke , M L 2017 , ' A highly active manganese catalyst for enantioselective ketone and ester hydrogenation ' , Angewandte Chemie , vol. 129 , no. 21 , pp. 5919-5922 . https://doi.org/10.1002/ange.201702406 | en |
dc.identifier.issn | 0044-8249 | |
dc.identifier.other | ORCID: /0000-0002-5366-9168/work/32087327 | |
dc.identifier.other | ORCID: /0000-0002-9527-6418/work/56861910 | |
dc.identifier.other | ORCID: /0000-0002-2444-1244/work/59464632 | |
dc.identifier.uri | https://hdl.handle.net/10023/13175 | |
dc.description | We thank the EPSRC for DTG funding for M.B.W. and G.J.H. and for the use of the National Mass Spectrometry Service. The technical support staff at St Andrews are also gratefully acknowledged. The research data underpinning this paper can be accessed at: https://doi.org/10.17630/91ab7775-867c-4b21-97c7-7c9117269ada. | en |
dc.description.abstract | A new hydrogenation catalyst based on a manganese complex of a chiral P,N,N ligand has been found to be especially active for the hydrogenation of esters down to 0.1 mol% catalyst loading, and gives up to 97% e.e. in the hydrogenation of pro-chiral deactivated ketones at 30-50 oC. | |
dc.format.extent | 4 | |
dc.format.extent | 923394 | |
dc.language.iso | eng | |
dc.relation.ispartof | Angewandte Chemie | en |
dc.subject | Manganese | en |
dc.subject | Reduction | en |
dc.subject | Ester hydrogenation | en |
dc.subject | Ferrocene | en |
dc.subject | Enantioselective catalysis | en |
dc.subject | QD Chemistry | en |
dc.subject | TP Chemical technology | en |
dc.subject | DAS | en |
dc.subject.lcc | QD | en |
dc.subject.lcc | TP | en |
dc.title | A highly active manganese catalyst for enantioselective ketone and ester hydrogenation | en |
dc.type | Journal article | en |
dc.contributor.institution | University of St Andrews. School of Chemistry | en |
dc.contributor.institution | University of St Andrews. EaSTCHEM | en |
dc.identifier.doi | 10.1002/ange.201702406 | |
dc.description.status | Peer reviewed | en |
dc.date.embargoedUntil | 2018-04-20 | |
dc.identifier.url | http://onlinelibrary.wiley.com/doi/10.1002/ange.201702406/full#footer-support-info | en |
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