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Scope and limitations of a DMF bio-alternative within Sonogashira cross-coupling and Cacchi-type annulation
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dc.contributor.author | Wilson, Kirsty | |
dc.contributor.author | Kennedy, Alan | |
dc.contributor.author | Murray, Jane | |
dc.contributor.author | Greatex, Ben | |
dc.contributor.author | Jamieson, Craig | |
dc.contributor.author | Watson, Allan | |
dc.date.accessioned | 2018-02-07T15:30:08Z | |
dc.date.available | 2018-02-07T15:30:08Z | |
dc.date.issued | 2016-09-08 | |
dc.identifier | 252198665 | |
dc.identifier | c2155a44-1bb0-4f49-8664-56cadccb53e2 | |
dc.identifier | 84988697854 | |
dc.identifier.citation | Wilson , K , Kennedy , A , Murray , J , Greatex , B , Jamieson , C & Watson , A 2016 , ' Scope and limitations of a DMF bio-alternative within Sonogashira cross-coupling and Cacchi-type annulation ' , Beilstein Journal of Organic Chemistry , vol. 12 , pp. 2005-2011 . https://doi.org/10.3762/bjoc.12.187 | en |
dc.identifier.issn | 1860-5397 | |
dc.identifier.other | RIS: urn:E94AD5EE22332517878537149D605300 | |
dc.identifier.other | ORCID: /0000-0002-1582-4286/work/56639198 | |
dc.identifier.uri | https://hdl.handle.net/10023/12688 | |
dc.description | We thank the University of Strathclyde for a PhD studentship (KLW), Sigma-Aldrich for financial and material support, Circa for Cyrene, and the EPSRC UK National Mass Spectrometry Facility at Swansea University for analyses. | en |
dc.description.abstract | Pd-catalysed C-C bond formation is an essential tool within the pharmaceutical and agrochemical industries. Many of these reactions rely heavily on polar aprotic solvents; however, despite their utility, these solvents are incompatible with the drive towards more sustainable chemical synthesis. Herein, we describe the scope and limitations of an alternative to DMF derived from renewable sources (CyreneTM) in Sonogashira crosscoupling and Cacchi-type annulations. | |
dc.format.extent | 7 | |
dc.format.extent | 438265 | |
dc.language.iso | eng | |
dc.relation.ispartof | Beilstein Journal of Organic Chemistry | en |
dc.subject | Cacchi annulation | en |
dc.subject | Cross-coupling | en |
dc.subject | Heterocycles | en |
dc.subject | Sonogashira | en |
dc.subject | Sustainable solvent | en |
dc.subject | QD Chemistry | en |
dc.subject | NDAS | en |
dc.subject | SDG 7 - Affordable and Clean Energy | en |
dc.subject.lcc | QD | en |
dc.title | Scope and limitations of a DMF bio-alternative within Sonogashira cross-coupling and Cacchi-type annulation | en |
dc.type | Journal article | en |
dc.contributor.institution | University of St Andrews. School of Chemistry | en |
dc.identifier.doi | https://doi.org/10.3762/bjoc.12.187 | |
dc.description.status | Peer reviewed | en |
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