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dc.contributor.authorMcNerney, Brian
dc.contributor.authorMummadi, Suresh
dc.contributor.authorHung-Low, Fernando
dc.contributor.authorCordes, David B.
dc.contributor.authorUnruh, Daniel K.
dc.contributor.authorKrempner, Clemens
dc.date.accessioned2017-05-17T23:33:40Z
dc.date.available2017-05-17T23:33:40Z
dc.date.issued2016-08
dc.identifier.citationMcNerney , B , Mummadi , S , Hung-Low , F , Cordes , D B , Unruh , D K & Krempner , C 2016 , ' Synthesis and structure of sterically overloaded tetra-coordinated yttrium and lanthanum disiloxides ' , Inorganic Chemistry Communications , vol. 70 , pp. 103-106 . https://doi.org/10.1016/j.inoche.2016.05.016en
dc.identifier.issn1387-7003
dc.identifier.otherPURE: 242655088
dc.identifier.otherPURE UUID: 5ed03079-03f9-4277-87f9-0a1f5bb5344d
dc.identifier.otherRIS: urn:01661C4D10CE517FA8B70787514B423B
dc.identifier.otherScopus: 84973136640
dc.identifier.otherORCID: /0000-0002-5366-9168/work/28023980
dc.identifier.otherWOS: 000380865300024
dc.identifier.urihttp://hdl.handle.net/10023/10793
dc.descriptionThe NSF is thanked for purchase of a JEOL ECS-400 NMR Spectrometer (CRIF-MU CHE-1048553).en
dc.description.abstractThe synthesis, structures and reactivity of the spirocyclic yttrium and lanthanum disiloxides {[(CH2R2SiO)2]2M}H [M = Ln, Y; R = SiMe(SiMe3)2] 3 and 4 are reported. Compounds 3 and 4 were prepared from reactions of two equivalents of [CH2(R)2SiOH]2 [R = Si(SiMe3)2Me] ( 1 ) with one equivalent of M[N(SiMe3)2]2 (M = Y, La), respectively.
dc.format.extent4
dc.language.isoeng
dc.relation.ispartofInorganic Chemistry Communicationsen
dc.rights© 2016 Published by Elsevier B.V. This work is made available online in accordance with the publisher’s policies. This is the author created, accepted version manuscript following peer review and may differ slightly from the final published version. The final published version of this work is available at https://dx.doi.org/10.1016/j.inoche.2016.05.016en
dc.subjectSiloxideen
dc.subjectSilanolen
dc.subjectRare earth siloxideen
dc.subjectYttriumen
dc.subjectLanthanumen
dc.subjectQD Chemistryen
dc.subjectNDASen
dc.subject.lccQDen
dc.titleSynthesis and structure of sterically overloaded tetra-coordinated yttrium and lanthanum disiloxidesen
dc.typeJournal articleen
dc.description.versionPostprinten
dc.contributor.institutionUniversity of St Andrews. School of Chemistryen
dc.contributor.institutionUniversity of St Andrews. EaSTCHEMen
dc.identifier.doihttps://doi.org/10.1016/j.inoche.2016.05.016
dc.description.statusPeer revieweden
dc.date.embargoedUntil2017-05-17


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