Synthesis and structure of sterically overloaded tetra-coordinated yttrium and lanthanum disiloxides

McNerney, Brian; Mummadi, Suresh; Hung-Low, Fernando; Cordes, David B.; Unruh, Daniel K.; Krempner, Clemens

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dc.contributor.author	McNerney, Brian
dc.contributor.author	Mummadi, Suresh
dc.contributor.author	Hung-Low, Fernando
dc.contributor.author	Cordes, David B.
dc.contributor.author	Unruh, Daniel K.
dc.contributor.author	Krempner, Clemens
dc.date.accessioned	2017-05-17T23:33:40Z
dc.date.available	2017-05-17T23:33:40Z
dc.date.issued	2016-08
dc.identifier	242655088
dc.identifier	5ed03079-03f9-4277-87f9-0a1f5bb5344d
dc.identifier	84973136640
dc.identifier	000380865300024
dc.identifier.citation	McNerney , B , Mummadi , S , Hung-Low , F , Cordes , D B , Unruh , D K & Krempner , C 2016 , ' Synthesis and structure of sterically overloaded tetra-coordinated yttrium and lanthanum disiloxides ' , Inorganic Chemistry Communications , vol. 70 , pp. 103-106 . https://doi.org/10.1016/j.inoche.2016.05.016	en
dc.identifier.issn	1387-7003
dc.identifier.other	RIS: urn:01661C4D10CE517FA8B70787514B423B
dc.identifier.other	ORCID: /0000-0002-5366-9168/work/28023980
dc.identifier.uri	https://hdl.handle.net/10023/10793
dc.description	The NSF is thanked for purchase of a JEOL ECS-400 NMR Spectrometer (CRIF-MU CHE-1048553).	en
dc.description.abstract	The synthesis, structures and reactivity of the spirocyclic yttrium and lanthanum disiloxides {[(CH2R2SiO)2]2M}H [M = Ln, Y; R = SiMe(SiMe3)2] 3 and 4 are reported. Compounds 3 and 4 were prepared from reactions of two equivalents of [CH2(R)2SiOH]2 [R = Si(SiMe3)2Me] ( 1 ) with one equivalent of M[N(SiMe3)2]2 (M = Y, La), respectively.
dc.format.extent	4
dc.format.extent	1037175
dc.language.iso	eng
dc.relation.ispartof	Inorganic Chemistry Communications	en
dc.subject	Siloxide	en
dc.subject	Silanol	en
dc.subject	Rare earth siloxide	en
dc.subject	Yttrium	en
dc.subject	Lanthanum	en
dc.subject	QD Chemistry	en
dc.subject	NDAS	en
dc.subject.lcc	QD	en
dc.title	Synthesis and structure of sterically overloaded tetra-coordinated yttrium and lanthanum disiloxides	en
dc.type	Journal article	en
dc.contributor.institution	University of St Andrews. School of Chemistry	en
dc.contributor.institution	University of St Andrews. EaSTCHEM	en
dc.identifier.doi	https://doi.org/10.1016/j.inoche.2016.05.016
dc.description.status	Peer reviewed	en
dc.date.embargoedUntil	2017-05-17

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