Synthesis and structure of sterically overloaded tetra-coordinated yttrium and lanthanum disiloxides
Abstract
The synthesis, structures and reactivity of the spirocyclic yttrium and lanthanum disiloxides {[(CH2R2SiO)2]2M}H [M = Ln, Y; R = SiMe(SiMe3)2] 3 and 4 are reported. Compounds 3 and 4 were prepared from reactions of two equivalents of [CH2(R)2SiOH]2 [R = Si(SiMe3)2Me] ( 1 ) with one equivalent of M[N(SiMe3)2]2 (M = Y, La), respectively.
Citation
McNerney , B , Mummadi , S , Hung-Low , F , Cordes , D B , Unruh , D K & Krempner , C 2016 , ' Synthesis and structure of sterically overloaded tetra-coordinated yttrium and lanthanum disiloxides ' , Inorganic Chemistry Communications , vol. 70 , pp. 103-106 . https://doi.org/10.1016/j.inoche.2016.05.016
Publication
Inorganic Chemistry Communications
Status
Peer reviewed
ISSN
1387-7003Type
Journal article
Rights
© 2016 Published by Elsevier B.V. This work is made available online in accordance with the publisher’s policies. This is the author created, accepted version manuscript following peer review and may differ slightly from the final published version. The final published version of this work is available at https://dx.doi.org/10.1016/j.inoche.2016.05.016
Description
The NSF is thanked for purchase of a JEOL ECS-400 NMR Spectrometer (CRIF-MU CHE-1048553).Collections
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