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Two novel self-interpenetrating 3D iron(II) coordination frameworks : synthesis, spectroscopic and structural characterizations with magnetic properties
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dc.contributor.author | Setifi, Zouaoui | |
dc.contributor.author | Addala, Abderazzak | |
dc.contributor.author | Tao, Jun | |
dc.contributor.author | Wannarit, Nanthawat | |
dc.contributor.author | Glidewell, Christopher | |
dc.contributor.author | Setifi, Fatima | |
dc.contributor.author | Youngme, Sujittra | |
dc.date.accessioned | 2017-04-17T04:38:23Z | |
dc.date.available | 2017-04-17T04:38:23Z | |
dc.date.issued | 2016-06-01 | |
dc.identifier | 242181016 | |
dc.identifier | 3fe3d4d4-5a5c-4340-b8c0-3a30bcc3760e | |
dc.identifier | 84964981914 | |
dc.identifier | 000376711600019 | |
dc.identifier.citation | Setifi , Z , Addala , A , Tao , J , Wannarit , N , Glidewell , C , Setifi , F & Youngme , S 2016 , ' Two novel self-interpenetrating 3D iron(II) coordination frameworks : synthesis, spectroscopic and structural characterizations with magnetic properties ' , Inorganic Chemistry Communications , vol. 68 , pp. 80-84 . https://doi.org/10.1016/j.inoche.2016.04.005 | en |
dc.identifier.issn | 1387-7003 | |
dc.identifier.other | RIS: urn:F7D4B93187C4844EA82D9F9F3337D009 | |
dc.identifier.uri | https://hdl.handle.net/10023/10621 | |
dc.description | The authors acknowledge the algerian MESRS (Ministère de l'Enseignement Supérieur et de la Recherche Scientifique), the algerian DG-RSDT (Direction Générale de la Recherche Scientifique et du Développement Technologique) and Ferhat Abbas University for financial support. SY acknowledges The Thailand Research Fund (Grant No. BRG5680009), the National Research University Project of Thailand, Office of the Higher Education Commission, and the Center of Excellence for Innovation in Chemistry (PERCH-CIC), Office of the Higher Education Commission, Ministry of Education, Thailand. NW thanks Central Scientific Instrument Center (CSIC), Faculty of Science and Technology, Thammasat University, Thailand. | en |
dc.description.abstract | Two novel self-interpenetrating 3D Fe(II) coordination frameworks namely {Fe(4,4′-bpy)[Ag2(CN)3]2}n ( I ) and {Fe(4,4′-bpy)[Ag(CN)2]2[AgCN]2}n ( II ) have been synthesized and fully characterized. The 3D architectures and degree of interpenetration of these coordination frameworks were significantly affected by silver(I) cyanide species. The crystal structure of I presents 4-fold interpenetrating 3D framework with 4,4′-bpy and [Ag2(CN)3]− species. While, that of II constructed by 4,4′-bpy and two different silver(I) cyanide species, AgCN and [Ag(CN)2]− resulting to 2-fold interpenetrating 3D framework. The stability and rigidity of both coordination frameworks are mainly supported dominantly by AgI ⋯ AgI interactions. Their magnetic properties exhibit high spin behavior. | |
dc.format.extent | 5 | |
dc.format.extent | 1104263 | |
dc.language.iso | eng | |
dc.relation.ispartof | Inorganic Chemistry Communications | en |
dc.subject | Fe(II) coordination frameworks | en |
dc.subject | Self-interpenetrate | en |
dc.subject | AgI ⋯ AgI | en |
dc.subject | Magnetic properties | en |
dc.subject | QD Chemistry | en |
dc.subject | DAS | en |
dc.subject.lcc | QD | en |
dc.title | Two novel self-interpenetrating 3D iron(II) coordination frameworks : synthesis, spectroscopic and structural characterizations with magnetic properties | en |
dc.type | Journal article | en |
dc.contributor.institution | University of St Andrews. School of Chemistry | en |
dc.identifier.doi | https://doi.org/10.1016/j.inoche.2016.04.005 | |
dc.description.status | Peer reviewed | en |
dc.date.embargoedUntil | 2017-04-16 |
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