Two novel self-interpenetrating 3D iron(II) coordination frameworks : synthesis, spectroscopic and structural characterizations with magnetic properties
Abstract
Two novel self-interpenetrating 3D Fe(II) coordination frameworks namely {Fe(4,4′-bpy)[Ag2(CN)3]2}n ( I ) and {Fe(4,4′-bpy)[Ag(CN)2]2[AgCN]2}n ( II ) have been synthesized and fully characterized. The 3D architectures and degree of interpenetration of these coordination frameworks were significantly affected by silver(I) cyanide species. The crystal structure of I presents 4-fold interpenetrating 3D framework with 4,4′-bpy and [Ag2(CN)3]− species. While, that of II constructed by 4,4′-bpy and two different silver(I) cyanide species, AgCN and [Ag(CN)2]− resulting to 2-fold interpenetrating 3D framework. The stability and rigidity of both coordination frameworks are mainly supported dominantly by AgI ⋯ AgI interactions. Their magnetic properties exhibit high spin behavior.
Citation
Setifi , Z , Addala , A , Tao , J , Wannarit , N , Glidewell , C , Setifi , F & Youngme , S 2016 , ' Two novel self-interpenetrating 3D iron(II) coordination frameworks : synthesis, spectroscopic and structural characterizations with magnetic properties ' , Inorganic Chemistry Communications , vol. 68 , pp. 80-84 . https://doi.org/10.1016/j.inoche.2016.04.005
Publication
Inorganic Chemistry Communications
Status
Peer reviewed
ISSN
1387-7003Type
Journal article
Description
The authors acknowledge the algerian MESRS (Ministère de l'Enseignement Supérieur et de la Recherche Scientifique), the algerian DG-RSDT (Direction Générale de la Recherche Scientifique et du Développement Technologique) and Ferhat Abbas University for financial support. SY acknowledges The Thailand Research Fund (Grant No. BRG5680009), the National Research University Project of Thailand, Office of the Higher Education Commission, and the Center of Excellence for Innovation in Chemistry (PERCH-CIC), Office of the Higher Education Commission, Ministry of Education, Thailand. NW thanks Central Scientific Instrument Center (CSIC), Faculty of Science and Technology, Thammasat University, Thailand.Collections
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