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dc.contributor.authorJeon, Yukwon
dc.contributor.authorMyung, Jae-ha
dc.contributor.authorHyun, Sang-hoon
dc.contributor.authorShul, Yong-gun
dc.contributor.authorIrvine, John T. S.
dc.date.accessioned2017-01-16T12:30:13Z
dc.date.available2017-01-16T12:30:13Z
dc.date.issued2017-02-28
dc.identifier.citationJeon , Y , Myung , J , Hyun , S , Shul , Y & Irvine , J T S 2017 , ' Corn-cob like nanofibres as cathode catalysts for an effective microstructure design in solid oxide fuel cells ' , Journal of Materials Chemistry A , vol. 5 , no. 8 , pp. 3966-3973 . https://doi.org/10.1039/C6TA08692Fen
dc.identifier.issn2050-7488
dc.identifier.otherPURE: 248897663
dc.identifier.otherPURE UUID: 7eecbb6c-f621-42a2-9dfe-7bd74a9156f4
dc.identifier.otherScopus: 85013755151
dc.identifier.otherWOS: 000395309800023
dc.identifier.otherORCID: /0000-0002-8394-3359/work/68280590
dc.identifier.urihttp://hdl.handle.net/10023/10109
dc.descriptionThis research was supported by the New & Renewable Energy Core Technology Program of the Korea Institute of Energy Technology Evaluation and Planning (KETEP) with a financial resource from the Ministry of Trade, Industry & Energy (No. 20133030011320).en
dc.description.abstractAn efficient cathode for solid oxide fuel cell (SOFC) is mainly determined by the oxygen reduction reaction (ORR) activity of the mixed materials. We demonstrate a new microstructure design through a nanofibrous electrode based on an unique corn-cob structure. One-step process to produce a corn-cob ceramic nanofiber of La0.8Sr0.2MnO3 (LSM) and Y2O3-stabilized ZrO2 (YSZ) is introduced by an electrospinning equipped with a coaxial nozzel. From the microscope analysis, perfect corn-cob nanofibers are finely produced with the diameter of 350 nm for a core and nanoparticles (30-40 nm) stacked on the surface like as a core-shell structure. The cathode fabricated by nanofibers with LSM outside and YSZ inside (YSZ@LSM) shows the best maximum power density of 1.15 Wcm-2 at 800 oC with low polarization resistance, which is higher than the reverse core and shell positions (LSM@YSZ) and even the commercial LSM-YSZ. This better outcome is more obvious at the elevated temperature due to the accelerated catalytic activity. Therefore, we could find the insight into the key factors enhancing the ORR activity and single cell performance in terms of not only the nanofibrous core@shell structure but also more reaction active sites from the optimum catalyst position at the designed corn-cob nanofibers based cathodes.
dc.format.extent8
dc.language.isoeng
dc.relation.ispartofJournal of Materials Chemistry Aen
dc.rights© 2017, The Authors. This work has been made available online in accordance with the publisher’s policies. This is the author created, accepted version manuscript following peer review and may differ slightly from the final published version. The final published version of this work is available at: https://doi.org/10.1039/C6TA08692Fen
dc.subjectQD Chemistryen
dc.subjectNDASen
dc.subject.lccQDen
dc.titleCorn-cob like nanofibres as cathode catalysts for an effective microstructure design in solid oxide fuel cellsen
dc.typeJournal articleen
dc.description.versionPreprinten
dc.description.versionPostprinten
dc.contributor.institutionUniversity of St Andrews.School of Chemistryen
dc.contributor.institutionUniversity of St Andrews.EaSTCHEMen
dc.identifier.doihttps://doi.org/10.1039/C6TA08692F
dc.description.statusPeer revieweden
dc.date.embargoedUntil2018-01-09


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