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Zirconium trisulfide as a promising cathode material for Li primary thermal batteries
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dc.contributor.author | Giagloglou, Kyriakos | |
dc.contributor.author | Payne, Julia Louise | |
dc.contributor.author | Crouch, Christina | |
dc.contributor.author | Gover, Richard | |
dc.contributor.author | Connor, Paul Alexander | |
dc.contributor.author | Irvine, John Thomas Sirr | |
dc.date.accessioned | 2016-12-07T12:30:09Z | |
dc.date.available | 2016-12-07T12:30:09Z | |
dc.date.issued | 2016-11-25 | |
dc.identifier | 247757471 | |
dc.identifier | f3a042ec-aec2-4c5d-9c3b-58bd87a726e1 | |
dc.identifier | 85006482289 | |
dc.identifier | 000393852200036 | |
dc.identifier.citation | Giagloglou , K , Payne , J L , Crouch , C , Gover , R , Connor , P A & Irvine , J T S 2016 , ' Zirconium trisulfide as a promising cathode material for Li primary thermal batteries ' , Journal of The Electrochemical Society , vol. 163 , no. 14 . https://doi.org/10.1149/2.1351614jes | en |
dc.identifier.issn | 0013-4651 | |
dc.identifier.other | ORCID: /0000-0002-1492-7590/work/60427185 | |
dc.identifier.other | ORCID: /0000-0003-3324-6018/work/60888219 | |
dc.identifier.other | ORCID: /0000-0002-8394-3359/work/68280589 | |
dc.identifier.uri | https://hdl.handle.net/10023/9943 | |
dc.description.abstract | In this work ZrS3 has been synthesized by solid state reaction in a sealed quartz tube and investigated as a candidate cathode material in Li thermal batteries. The structure of ZrS3 before and after cell testing has been studied using powder X-ray diffraction. A new spinel related material, LiZr2S4, has been identified as the product of the electrochemical process, which can be indexed to a = 10.452(8) Å cubic unit cell. The electrochemical properties of the batteries were investigated at 500 °C against Li13Si4 by galvanostatic discharge and galvanostatic intermittent titration technique (GITT). In a thermal Li cell at 500 °C a single voltage plateau of 1.70 V at a current density of 11 mA/cm2 was achieved with capacity of 357 mA h g-1. Therefore ZrS3 material has some promise as a cathode for Li thermal batteries. | |
dc.format.extent | 953218 | |
dc.language.iso | eng | |
dc.relation.ispartof | Journal of The Electrochemical Society | en |
dc.subject | Cathode | en |
dc.subject | Discharge at high temperature | en |
dc.subject | Li thermal battery | en |
dc.subject | LiZr2S4 | en |
dc.subject | Solid state reaction | en |
dc.subject | ZrS | en |
dc.subject | QD Chemistry | en |
dc.subject | NDAS | en |
dc.subject.lcc | QD | en |
dc.title | Zirconium trisulfide as a promising cathode material for Li primary thermal batteries | en |
dc.type | Journal article | en |
dc.contributor.sponsor | EPSRC | en |
dc.contributor.sponsor | The Royal Society | en |
dc.contributor.institution | University of St Andrews. School of Chemistry | en |
dc.contributor.institution | University of St Andrews. EaSTCHEM | en |
dc.contributor.institution | University of St Andrews. St Andrews Sustainability Institute | en |
dc.identifier.doi | https://doi.org/10.1149/2.1351614jes | |
dc.description.status | Peer reviewed | en |
dc.identifier.grantnumber | EP/K015540/1 | en |
dc.identifier.grantnumber | WRMA 2012/R2 | en |
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