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The preparation and characterisation of rhodium(III) and Iridium(III) half sandwich complexes with napthalene-1,8-dithiolate, acenaphthene-5,6-dithiolate and biphenyl-2,2′-dithiolate
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dc.contributor.author | Nejman, P.S. | |
dc.contributor.author | Morton-Fernandez, B. | |
dc.contributor.author | Black, N. | |
dc.contributor.author | Cordes, D.B. | |
dc.contributor.author | Slawin, A.M.Z. | |
dc.contributor.author | Kilian, P. | |
dc.contributor.author | Woollins, J.D. | |
dc.date.accessioned | 2016-11-01T00:33:13Z | |
dc.date.available | 2016-11-01T00:33:13Z | |
dc.date.issued | 2015-01-15 | |
dc.identifier | 159054174 | |
dc.identifier | acd859ce-3bec-45b1-a271-18e35ec1d246 | |
dc.identifier | 84910649499 | |
dc.identifier | 000346636800002 | |
dc.identifier.citation | Nejman , P S , Morton-Fernandez , B , Black , N , Cordes , D B , Slawin , A M Z , Kilian , P & Woollins , J D 2015 , ' The preparation and characterisation of rhodium(III) and Iridium(III) half sandwich complexes with napthalene-1,8-dithiolate, acenaphthene-5,6-dithiolate and biphenyl-2,2′-dithiolate ' , Journal of Organometallic Chemistry , vol. 776 , pp. 7-16 . https://doi.org/10.1016/j.jorganchem.2014.10.023 | en |
dc.identifier.issn | 0022-328X | |
dc.identifier.other | ORCID: /0000-0002-5366-9168/work/28024015 | |
dc.identifier.other | ORCID: /0000-0002-9527-6418/work/56861784 | |
dc.identifier.other | ORCID: /0000-0001-6379-3026/work/58285406 | |
dc.identifier.other | ORCID: /0000-0002-1498-9652/work/31779188 | |
dc.identifier.uri | https://hdl.handle.net/10023/9743 | |
dc.description.abstract | The synthesis of rhodium(III) and iridium (III) half sandwich complexes [Cp*M(PEt3) (S-R-S)], M = Rh, Ir; S-R-S = naphthalene-1,8-dithiolate (NaphthS2, a), acenaphthene-5,6-dithiolate (AcenapS2, b) and biphenyl-2,2′-dithiolate (BiphenS2, c) is reported. We also describe the isolation of a new compound acenaphthene-1,8-dithiol. All complexes have been fully characterised using multinuclear NMR spectroscopy and single crystal X-ray diffraction. The ligands naphthalene-1,8-dithiol (H2a), acenaphthene-1,8-dithiol (H2b), 1,1′-biphenyl-2,2′-dithiol (H2c) and benzene-1,2-dithiol (H2d) have also been characterised by single crystal X-ray diffraction. | |
dc.format.extent | 10 | |
dc.format.extent | 1294800 | |
dc.language.iso | eng | |
dc.relation.ispartof | Journal of Organometallic Chemistry | en |
dc.subject | Sulfur | en |
dc.subject | Bidentate | en |
dc.subject | Iridium | en |
dc.subject | Rhodium | en |
dc.subject | Half sandwich | en |
dc.subject | phosphine | en |
dc.subject | QD Chemistry | en |
dc.subject | DAS | en |
dc.subject.lcc | QD | en |
dc.title | The preparation and characterisation of rhodium(III) and Iridium(III) half sandwich complexes with napthalene-1,8-dithiolate, acenaphthene-5,6-dithiolate and biphenyl-2,2′-dithiolate | en |
dc.type | Journal article | en |
dc.contributor.sponsor | EPSRC | en |
dc.contributor.sponsor | EPSRC | en |
dc.contributor.institution | University of St Andrews. School of Chemistry | en |
dc.contributor.institution | University of St Andrews. EaSTCHEM | en |
dc.contributor.institution | University of St Andrews. Office of the Principal | en |
dc.identifier.doi | 10.1016/j.jorganchem.2014.10.023 | |
dc.description.status | Peer reviewed | en |
dc.date.embargoedUntil | 2016-10-31 | |
dc.identifier.url | http://www.sciencedirect.com/science/article/pii/S0022328X14004999#appd001 | en |
dc.identifier.grantnumber | EP/K031252/1 | en |
dc.identifier.grantnumber | EP/K039210/1 | en |
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