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Catalytic stereoselective [2,3]-rearrangement reactions

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dc.contributor.authorWest, Thomas Henry
dc.contributor.authorSpoehrle, Stephanie Suzanne Madeleine
dc.contributor.authorKasten, Kevin
dc.contributor.authorTaylor, James Edward
dc.contributor.authorSmith, Andrew David
dc.date.accessioned2016-10-29T23:33:54Z
dc.date.available2016-10-29T23:33:54Z
dc.date.issued2015
dc.identifier228188234
dc.identifiera4851398-1b1a-4731-ae2d-a38bb03a5a21
dc.identifier84948845064
dc.identifier000366153300045
dc.identifier.citationWest , T H , Spoehrle , S S M , Kasten , K , Taylor , J E & Smith , A D 2015 , ' Catalytic stereoselective [2,3]-rearrangement reactions ' , ACS Catalysis , vol. In press . https://doi.org/10.1021/acscatal.5b02070en
dc.identifier.issn2155-5435
dc.identifier.otherORCID: /0000-0002-2104-7313/work/36567496
dc.identifier.urihttps://hdl.handle.net/10023/9734
dc.descriptionThe authors thank the Royal Society for a University Research Fellowship (A.D.S.), the European Research Council under the European Union’s Seventh Framework Programme (FP7/2007-20013) ERC Grant Agreement No. 279850 (J.E.T., T.H.W., K.K.), and the European Union (Marie Curie ITN ‘SuBiCat’ PITN-GA-2013-607044) (S.S.M.S.) for financial support.en
dc.description.abstract[2,3]-Sigmatropic rearrangement processes of allylic ylides or their equivalents can be applied to a variety of different substrates and generate products of wide interest and applicability to organic synthesis. This review describes the development and applications of stereoselective [2,3]-rearrangement reactions in which a sub-stoichiometric amount of a catalyst is used in either the formation of the reactive intermediate or the [2,3]-rearrangement step itself.
dc.format.extent1119605
dc.language.isoeng
dc.relation.ispartofACS Catalysisen
dc.subjectStereoselective catalysisen
dc.subject[2,3]-rearrangementen
dc.subjectAllylic oxonium ylidesen
dc.subjectAllylic ammonium ylidesen
dc.subjectO-propargylic oximesen
dc.subjectAllylic sulfoxidesen
dc.subjectAllylic N-oxidesen
dc.subjectQD Chemistryen
dc.subjectNDASen
dc.subject.lccQDen
dc.titleCatalytic stereoselective [2,3]-rearrangement reactionsen
dc.typeJournal articleen
dc.contributor.sponsorMarie Curie Fellowshipsen
dc.contributor.sponsorThe Royal Societyen
dc.contributor.institutionUniversity of St Andrews. School of Chemistryen
dc.contributor.institutionUniversity of St Andrews. Biomedical Sciences Research Complexen
dc.contributor.institutionUniversity of St Andrews. EaSTCHEMen
dc.identifier.doihttps://doi.org/10.1021/acscatal.5b02070
dc.description.statusPeer revieweden
dc.date.embargoedUntil2016-10-29
dc.identifier.grantnumberSUBICATen
dc.identifier.grantnumberen


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