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dc.contributor.authorDo, Truong Giang
dc.contributor.authorHupf, Emanuel
dc.contributor.authorNordheider, Andreas
dc.contributor.authorLork, Enno
dc.contributor.authorSlawin, Alexandra Martha Zoya
dc.contributor.authorMakarov, Sergey G.
dc.contributor.authorKetkov, Sergey Yu.
dc.contributor.authorMebs, Stefan
dc.contributor.authorWoollins, J Derek
dc.contributor.authorBeckman, Jens
dc.date.accessioned2016-10-28T23:34:03Z
dc.date.available2016-10-28T23:34:03Z
dc.date.issued2015-11-09
dc.identifier.citationDo , T G , Hupf , E , Nordheider , A , Lork , E , Slawin , A M Z , Makarov , S G , Ketkov , S Y , Mebs , S , Woollins , J D & Beckman , J 2015 , ' Intramolecularly group 15 stabilized aryltellurenyl halides and triflates ' Organometallics , vol. 34 , no. 21 , pp. 5341–5360 . https://doi.org/10.1021/acs.organomet.5b00813en
dc.identifier.issn0276-7333
dc.identifier.otherPURE: 225038426
dc.identifier.otherPURE UUID: ee9a3d40-a264-400b-9d64-db20d5b2b9bf
dc.identifier.otherScopus: 84946710935
dc.identifier.otherORCID: /0000-0002-9527-6418/work/56861622
dc.identifier.otherORCID: /0000-0002-1498-9652/work/31779169
dc.identifier.otherWOS: 000364614400016
dc.identifier.urihttp://hdl.handle.net/10023/9730
dc.descriptionThe Deutsche Forschungsgemeinschaft (DFG) is gratefully acknowledged for financial support. The energy decomposition and deformation electron density analyses were carried out within the framework of the Project 14-13-00832 supported by the Russian Science Foundation.en
dc.description.abstractThe preparation of a series of functionalized peri-substituted acenaphthyl compounds 6-Ph2E-Ace-5-Br (1, E = As; 2, E = Sb), 6-Ph2As-Ace-5-TeMes (3), 5-I-Ace-6-TeMes (4), 6-Ph2Sb-Ace-5-TeMes (5), (6-Ph2P-Ace-5)2Te (6), [6-R2E-Ace-5-Te]X (7, E = P, R = Ph, X = Cl; 8, E = P, R = i-Pr, X = Cl; 9, E = P, R = i-Pr, X = Br; 10, E = P, R = i-Pr, X = I; 11, E = P, R = i-Pr, X = ½ (TeI6); 12, E = P, R = i-Pr, X = I3; 13, E = P, R = Ph, X = O3SCF3; 14, E = As, R = Ph, X = O3SCF3; 15, E = Sb, R = Ph, X = O3SCF3) and [6-PhSb-Ace-5-TeMes]O3SCF3 (16) was reported (Ace = acenaphthyl). The synthesis of 7-15 was either achieved by salt metathesis reaction of 5-i-Pr2P-Ace-6-Li with TeCl2∙TMTU (8), TeBr2∙TMTU (9) and TeI4 (10 + 11) or by the aryl cleavage reaction of 6-R2E-Ace-5-TeMes (E = P, As, Sb; R = Ph, i-Pr) with HgCl2 (7), I2 (12) and HO3SCF3 (13-15). The reaction of 5 with triflic acid gave also rise to the formation of [6-PhSb-Ace-5-TeMes]O3SCF3 (16). All compounds have been characterized by multinuclear NMR spectroscopy and single crystal X-ray diffraction. Complementary DFT studies including relaxed potential energy scans (PES) and subsequent topological analysis of the resulting electron and pair densities according to the AIM and ELI-D partitioning schemes are performed for the aryltellurenyl chlorides [6-Ph2P-Ace-5-Te]Cl, [8-Me2N-Nap-1-Te]Cl and [8-Me2P-Nap-1-Te]Cl in the gas phase and in MeCN solution, whereby the Te-Cl distances were systematically varied. The same analyses were carried out for the fully optimized [6-R2E-Ace-5-Te]+ cations (E = P, As, Sb) and compared to those of the previously studied intermolecularly stabilized [R3ETeMes]+ cations (E = P, As, Sb).
dc.language.isoeng
dc.relation.ispartofOrganometallicsen
dc.rightsCopyright © 2015 American Chemical Society. This work is made available online in accordance with the publisher’s policies. This is the author created, accepted version manuscript following peer review and may differ slightly from the final published version. The final published version of this work is available at https://dx.doi.org/10.1021/acs.organomet.5b00813en
dc.subjectQD Chemistryen
dc.subjectDASen
dc.subject.lccQDen
dc.titleIntramolecularly group 15 stabilized aryltellurenyl halides and triflatesen
dc.typeJournal articleen
dc.description.versionPostprinten
dc.contributor.institutionUniversity of St Andrews.School of Chemistryen
dc.contributor.institutionUniversity of St Andrews.Office of the Principalen
dc.contributor.institutionUniversity of St Andrews.EaSTCHEMen
dc.identifier.doihttps://doi.org/10.1021/acs.organomet.5b00813
dc.description.statusPeer revieweden
dc.date.embargoedUntil2016-10-28
dc.identifier.urlhttp://pubs.acs.org/doi/suppl/10.1021/acs.organomet.5b00813en


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