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Structural tailoring of the NIR-absorption of bis(1,2-dichalcogenolene) Ni/Pt electrochromophores deriving from 1,3-dimethyl-2-chalcogenoxo-imidazoline-4,5-dichalcogenolates

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dc.contributor.authorDeiana, Carlo
dc.contributor.authorAragoni, M. Carla
dc.contributor.authorIsaia, Francesco
dc.contributor.authorLippolis, Vito
dc.contributor.authorPintus, Anna
dc.contributor.authorSlawin, Alexandra M. Z.
dc.contributor.authorWoollins, J. Derek
dc.contributor.authorArca, Massimiliano
dc.date.accessioned2016-10-20T10:30:11Z
dc.date.available2016-10-20T10:30:11Z
dc.date.issued2016-10-01
dc.identifier.citationDeiana , C , Aragoni , M C , Isaia , F , Lippolis , V , Pintus , A , Slawin , A M Z , Woollins , J D & Arca , M 2016 , ' Structural tailoring of the NIR-absorption of bis(1,2-dichalcogenolene) Ni/Pt electrochromophores deriving from 1,3-dimethyl-2-chalcogenoxo-imidazoline-4,5-dichalcogenolates ' , New Journal of Chemistry , vol. 40 , no. 10 , pp. 8206-8210 . https://doi.org/10.1039/C6NJ01854Hen
dc.identifier.issn1144-0546
dc.identifier.otherPURE: 244923746
dc.identifier.otherPURE UUID: 75e11b8e-39fb-489d-ab39-3437b159432f
dc.identifier.otherScopus: 84989965478
dc.identifier.otherORCID: /0000-0002-9527-6418/work/56861995
dc.identifier.otherORCID: /0000-0002-1498-9652/work/31779157
dc.identifier.otherWOS: 000384754300005
dc.identifier.urihttps://hdl.handle.net/10023/9681
dc.descriptionThe Dipartimento di Scienze Chimiche e Geologiche of the Università degli Studi di Cagliari and Banco di Sardegna, Italy are kindly acknowledged for financial support (PRID 2015).en
dc.description.abstractThe choice of the metal ion M and the terminal Y and donor X chalcogen species (M = Ni, Pt; X, Y = S, Se) in square-planar complexes with 1,3-dimethyl-2-chalcogenoxo-imidazoline-4,5-dichalcogenolates allows fine-tuning both the redox stability and the energy of the peculiarly intense NIR electrochromic absorption, thanks to the subtle contribution of M, X, and Y to the relevant frontier molecular orbitals, investigated at IEF-PCM DFT and TD-DFT level.
dc.format.extent5
dc.language.isoeng
dc.relation.ispartofNew Journal of Chemistryen
dc.rightsCopyright 2016 the Authors. Open Access article. This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.en
dc.subjectQD Chemistryen
dc.subjectDASen
dc.subject.lccQDen
dc.titleStructural tailoring of the NIR-absorption of bis(1,2-dichalcogenolene) Ni/Pt electrochromophores deriving from 1,3-dimethyl-2-chalcogenoxo-imidazoline-4,5-dichalcogenolatesen
dc.typeJournal articleen
dc.description.versionPublisher PDFen
dc.contributor.institutionUniversity of St Andrews. School of Chemistryen
dc.contributor.institutionUniversity of St Andrews. EaSTCHEMen
dc.contributor.institutionUniversity of St Andrews. Office of the Principalen
dc.identifier.doihttps://doi.org/10.1039/C6NJ01854H
dc.description.statusPeer revieweden
dc.identifier.urlhttp://www.rsc.org/suppdata/c6/nj/c6nj01854h/c6nj01854h1.pdfen


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